{ "version": "materials-nbsctizr-annealing/1.0.0", "prepared_on": "2026-10-04", "status": "source_qualified_comparison", "material_label": "NbScTiZr", "authority": { "canonical_updates": 0, "scientific_acceptance": false, "formal_human_review": false, "ml_training_approved": false, "calculation_executed": false, "selected_result_sample_state_phase_association": "unestablished", "cross_publication_physical_sample_equivalence": "unestablished" }, "sources": [ { "id": "2023", "edition": "2311.00195v1", "title": "Effect of annealing in eutectic high-entropy alloy superconductor NbScTiZr", "source_url": "https://arxiv.org/pdf/2311.00195v1", "pdf_sha256": "5ada9ca574ae87d4cb4f8004a77a1504ce483b26642fe93d941e2c5d28ebd257", "pdf_bytes": 1131124, "pdf_pages": 18, "derived_text_sha256": "d571c998fe688f4c88c36cb648553e8ff7a696605ff15576c6ece7001e5f105e", "text_derivation": "pdftotext -layout UTF-8; page separators retained", "current_publication_status": "not_checked", "publisher_and_retained_ingestion_edition_equivalence": "unestablished", "supplement_checked": false }, { "id": "2024", "edition": "2406.19553v1", "title": "Superconducting properties of eutectic high-entropy alloy superconductor NbScTiZr", "source_url": "https://arxiv.org/pdf/2406.19553v1", "pdf_sha256": "2640697191af7398cbd39cd16cf5bf5b89514ccfbe56b40ce9c79103b5415119", "pdf_bytes": 2448451, "pdf_pages": 28, "derived_text_sha256": "790b589c41e0333169e3f38def64a64fbf340f363fe945a0d3bfd68c313b6555", "text_derivation": "pdftotext -layout UTF-8; page separators retained", "current_publication_status": "not_checked", "publisher_and_retained_ingestion_edition_equivalence": "unestablished", "supplement_checked": false } ], "samples": [ { "id": "as-cast", "label": "as-cast", "processing_temperature_value": null, "processing_temperature_unit": null, "processing_temperature_role": "as_cast_state_no_annealing_temperature", "processing_temperature_is_measurement_temperature": false, "hold_duration_value": null, "hold_duration_unit": null, "sample_listed_2023": true, "physical_sample_identity": "unestablished" }, { "id": "400-c", "label": "400 °C", "processing_temperature_value": "400", "processing_temperature_unit": "°C", "processing_temperature_role": "annealing_temperature", "processing_temperature_is_measurement_temperature": false, "hold_duration_value": "4", "hold_duration_unit": "days", "sample_listed_2023": true, "physical_sample_identity": "unestablished" }, { "id": "600-c", "label": "600 °C", "processing_temperature_value": "600", "processing_temperature_unit": "°C", "processing_temperature_role": "annealing_temperature", "processing_temperature_is_measurement_temperature": false, "hold_duration_value": "4", "hold_duration_unit": "days", "sample_listed_2023": false, "physical_sample_identity": "unestablished" }, { "id": "800-c", "label": "800 °C", "processing_temperature_value": "800", "processing_temperature_unit": "°C", "processing_temperature_role": "annealing_temperature", "processing_temperature_is_measurement_temperature": false, "hold_duration_value": "4", "hold_duration_unit": "days", "sample_listed_2023": true, "physical_sample_identity": "unestablished" }, { "id": "1000-c", "label": "1000 °C", "processing_temperature_value": "1000", "processing_temperature_unit": "°C", "processing_temperature_role": "annealing_temperature", "processing_temperature_is_measurement_temperature": false, "hold_duration_value": "4", "hold_duration_unit": "days", "sample_listed_2023": true, "physical_sample_identity": "unestablished" } ], "methods": [ { "id": "2023-preparation", "source_id": "2023", "summary": "Arc melting in argon on a water-cooled copper hearth; nominal Nb:Sc:Ti:Zr atomic ratio 1:1:1:1. Heat treatment at 400, 800 or 1000 °C for four days in an evacuated quartz tube.", "locator_ids": [ "2023-preparation" ] }, { "id": "2024-preparation", "source_id": "2024", "summary": "Arc melting in argon on a water-cooled copper hearth; nominal Nb:Sc:Ti:Zr atomic ratio 1:1:1:1. Annealing at 400, 600, 800 or 1000 °C for four days in an evacuated quartz tube.", "locator_ids": [ "2024-preparation" ] }, { "id": "2023-tc-definition", "source_id": "2023", "summary": "Figure 3(a) identifies Tc at ac-susceptibility diamagnetic onset. The ac setup uses 5 Oe at 800 Hz over 3–20 K. Resistivity zero is separately confirmed. The Table 1 values remain independent source expressions.", "locator_ids": [ "2023-probes", "2023-tc-onset" ] }, { "id": "2024-structure", "source_id": "2024", "summary": "Cu-Kα XRD with least-squares lattice parameter evaluation. The source attributes chemical composition to EDX coupled with field-emission SEM and cites the preceding study. Table 1 prints composition coefficients without an explicit composition unit.", "locator_ids": [ "2024-probes", "2024-phase-edx", "2024-table-1" ] }, { "id": "2024-m-and-rho", "source_id": "2024", "summary": "The text describes refined Tc from upper-critical-field analysis and M(T) diamagnetic-onset datasets analyzed with WHH. Resistivity transition onset yields a separate WHH channel. Table 2 values retain that Hc2-analysis context without assigning calorimetric midpoint or a common criterion across all probes.", "locator_ids": [ "2024-magnetic-onset", "2024-whh", "2024-refined-tc-analysis", "2024-resistive-onset", "2024-table-2" ] }, { "id": "2024-gl-derived", "source_id": "2024", "summary": "The source extrapolates Hc1(0) with a Ginzburg–Landau model. Coherence length is calculated from Hc2(0); penetration depth uses Hc1(0) and the matching coherence-length channel; κ is their ratio. These are source-derived estimates, not direct length measurements or electron–phonon coupling.", "locator_ids": [ "2024-lower-field-and-xi", "2024-lambda-and-kappa", "2024-table-2" ] }, { "id": "2024-specific-heat", "source_id": "2024", "summary": "Normal-state C/T versus T² fitting yields γel and β with both bcc and hcp contributions. Four annealed specimens receive exponential electronic-specific-heat gap fits plus a residual γ term attributed by the authors to hcp. The normalized heat-jump analysis explicitly uses transition midpoint Tc; this does not assign midpoint to the whole Table 2 Tc row.", "locator_ids": [ "2024-probes", "2024-normal-state-specific-heat", "2024-calorimetry", "2024-gap-jump" ] }, { "id": "2024-hardness", "source_id": "2024", "summary": "Vickers indentation is measured on polished surfaces with a 2.94 N load for ten seconds. Parentheses in source hardness and lattice values are preserved without interpreting uncertainties.", "locator_ids": [ "2024-probes", "2024-table-2" ] }, { "id": "2023-phase-volume", "source_id": "2023", "summary": "The source obtains phase volume fractions from SEM images and phase compositions from EDX. Its Table 1 lists composition-derived valence electron concentration separately. These are source phase reports, not superconducting volume fractions or catalogued atomic models.", "locator_ids": [ "2023-phase-volume", "2023-table-1" ] } ], "source_windows": [ { "id": "2024-table-1", "source_id": "2024", "pdf_page_one_based": 3, "char_start": 7009, "char_end": 8161, "end_exclusive": true, "window_sha256": "d42726faf99c23acc113ac551101c54f2f635b2dc199c49374b5a47ca7799e2d" }, { "id": "2024-table-2", "source_id": "2024", "pdf_page_one_based": 9, "char_start": 18173, "char_end": 20367, "end_exclusive": true, "window_sha256": "a72c368ef6e04d3473605ca71e069bccbd66b9df5f7b17925cce2eb1c92a1f93" }, { "id": "2023-table-1", "source_id": "2023", "pdf_page_one_based": 4, "char_start": 13116, "char_end": 14137, "end_exclusive": true, "window_sha256": "6eb2ec32b641bb7110d0d0aa46259d86f3581a912a45d50cacd88aa8c0448ec5" }, { "id": "2024-preparation", "source_id": "2024", "pdf_page_one_based": 4, "char_start": 9659, "char_end": 10201, "end_exclusive": true, "window_sha256": "52d60ff1af9763f178022f76a4b6ce6bd3a759c08c2c7a93107ca841710fe861" }, { "id": "2023-preparation", "source_id": "2023", "pdf_page_one_based": 3, "char_start": 9788, "char_end": 10382, "end_exclusive": true, "window_sha256": "e0de3222d9419ad72b20d968c2f6a1157f8208934a2bf639cb3eef6e0e6cb237" }, { "id": "2023-probes", "source_id": "2023", "pdf_page_one_based": 4, "char_start": 11150, "char_end": 12079, "end_exclusive": true, "window_sha256": "d622ff68dbf7090a4c300c89b1fbb658ebbd7d2d00c597b99316286bfa1fd2f5" }, { "id": "2023-tc-onset", "source_id": "2023", "pdf_page_one_based": 6, "char_start": 17829, "char_end": 18422, "end_exclusive": true, "window_sha256": "ee2ed15846b4e50548d770f9b08e4df43127db50d93e97e6948929f8858b4bce" }, { "id": "2023-phase-volume", "source_id": "2023", "pdf_page_one_based": 5, "char_start": 15503, "char_end": 16432, "end_exclusive": true, "window_sha256": "2d3e401fd10d734df37ad578e10d0d0c2a37423c389053bc53f8e1f7e9559c94" }, { "id": "2024-probes", "source_id": "2024", "pdf_page_one_based": 4, "char_start": 10201, "char_end": 11087, "end_exclusive": true, "window_sha256": "76b87bd59133825692b1469e52f57bf2c124b2c4ab146220c4f5dc7f37cc7984" }, { "id": "2024-phase-edx", "source_id": "2024", "pdf_page_one_based": 7, "char_start": 13352, "char_end": 13677, "end_exclusive": true, "window_sha256": "86aa7a3ad69ed0752ec2ecaf113e6f128ee8d63996cdc501e6e5ed483ad3874d" }, { "id": "2024-magnetic-onset", "source_id": "2024", "pdf_page_one_based": 7, "char_start": 15254, "char_end": 16205, "end_exclusive": true, "window_sha256": "86a5bcca75034f665438a1491e977b7bad00b39eb4a8d47f8f954fee29f6fafc" }, { "id": "2024-whh", "source_id": "2024", "pdf_page_one_based": 8, "char_start": 16505, "char_end": 18122, "end_exclusive": true, "window_sha256": "b5590ed2bbf5f322d2ca92787976e3217fdbd4a7de59be335a603fbcd2dbb215" }, { "id": "2024-resistive-onset", "source_id": "2024", "pdf_page_one_based": 9, "char_start": 20712, "char_end": 21610, "end_exclusive": true, "window_sha256": "36ab4b6bf4f941a4fe6a3703e038fae41da550f47685bc9e4f968ef039bab5b3" }, { "id": "2024-refined-tc-analysis", "source_id": "2024", "pdf_page_one_based": 9, "char_start": 20370, "char_end": 20712, "end_exclusive": true, "window_sha256": "79da506b12a39fc9c8c443ed81e35074c64af1df1174f4bdcb043043111a6b5e" }, { "id": "2024-lower-field-and-xi", "source_id": "2024", "pdf_page_one_based": 11, "char_start": 23874, "char_end": 25334, "end_exclusive": true, "window_sha256": "c44a2790b13a28f49a807942873ff40c1603466a5640fdca6ca0aa24d84b985b" }, { "id": "2024-lambda-and-kappa", "source_id": "2024", "pdf_page_one_based": 13, "char_start": 25867, "char_end": 26296, "end_exclusive": true, "window_sha256": "2f959730432e6f5129aad79b0826b8ccb694c633d12eef5fa5ef54890453ac5b" }, { "id": "2024-calorimetry", "source_id": "2024", "pdf_page_one_based": 17, "char_start": 35259, "char_end": 37148, "end_exclusive": true, "window_sha256": "9efa4b5762679307167a8113dbb7892392bf48bb7eb274a262d849054fbd04b9" }, { "id": "2024-normal-state-specific-heat", "source_id": "2024", "pdf_page_one_based": 17, "char_start": 35014, "char_end": 35259, "end_exclusive": true, "window_sha256": "ec39b4348b6ee23fa6dc85ed40da428829b7c061307b6e63f7baffe1c0ce9743" }, { "id": "2024-gap-jump", "source_id": "2024", "pdf_page_one_based": 17, "char_start": 37148, "char_end": 38136, "end_exclusive": true, "window_sha256": "570099b97c207ac5633531891af817e965d912b7098dbeec2c924c68938236db" } ], "phase_table": { "source_id": "2024", "source_locator_id": "2024-table-1", "label": "2024 Table 1: phase compositions and lattice parameters", "composition_unit": "not_printed_in_table", "composition_scope": "Original phase composition coefficients and parenthetical uncertainty notation; no stoichiometric conversion or catalogue sample equivalence.", "composition_source_attribution": "The 2024 text attributes bcc compositions to preceding study [46]. Its table is a source report, not an independently repeated composition measurement; 600 °C is not listed in the captured 2023 v1 Table 1.", "columns": [ "Nb", "Sc", "Ti", "Zr", "lattice_a", "lattice_c" ], "rows": [ { "sample_id": "as-cast", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "26.6(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7210, "char_end": 7217, "end_exclusive": true, "literal_sha256": "d8051c95bf8c43986ba2d21033b4786deab7de53a842b42392834bfcd74635e5" } }, "Sc": { "raw_value": "22.3(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7220, "char_end": 7227, "end_exclusive": true, "literal_sha256": "f457150d216d2f38c16db4da5ea1b693c57233663edf8faad88fc13198e9a320" } }, "Ti": { "raw_value": "25.5(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7230, "char_end": 7237, "end_exclusive": true, "literal_sha256": "4e5b03aba5765ec4d26fc81a848af3cb11110144a4e14622fd6b7f8b4114b0bc" } }, "Zr": { "raw_value": "25.6(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7240, "char_end": 7247, "end_exclusive": true, "literal_sha256": "640c3a92c10c884d74cbb911756b7155e0e8226a2639553991885f7dd2d5e64d" } }, "lattice_a": { "raw_value": "3.359(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7261, "char_end": 7269, "end_exclusive": true, "literal_sha256": "99c19934e9016190685dce3d2b09d8ef7de6257c9915fb5453276fb29d89a17d" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2024-table-1", "literal": null } } }, { "sample_id": "as-cast", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "21.3(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7289, "char_end": 7296, "end_exclusive": true, "literal_sha256": "33aa22d3b619d14333f80b0dd6f35e05e1ac1bfdf7625cd7ff2c50dee0beeff2" } }, "Sc": { "raw_value": "30(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7299, "char_end": 7304, "end_exclusive": true, "literal_sha256": "586fb8e5e81b7da643a8997d65b5a057e71f50e059fe266b19bd130c7f5cfa41" } }, "Ti": { "raw_value": "23.0(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7307, "char_end": 7314, "end_exclusive": true, "literal_sha256": "13f460e831f2d7882795fba6bfabe8ab20364a57b36b58e06560fb75abf6ff85" } }, "Zr": { "raw_value": "25.8(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7317, "char_end": 7324, "end_exclusive": true, "literal_sha256": "66b155403270a3cbab1b8b64ae284aeda2d06faca6d9e8038e62e5eaede68ac0" } }, "lattice_a": { "raw_value": "3.262(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7333, "char_end": 7341, "end_exclusive": true, "literal_sha256": "2d0b6a5973478fecb2b5c825dd504615ba328833f856916009a55c6cfe9108fd" } }, "lattice_c": { "raw_value": "5.152(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7345, "char_end": 7353, "end_exclusive": true, "literal_sha256": "8ea49a280e97a6bb4c4ded2270eb4078b2327fb6637d4a9630dc4a9c2fdb51a8" } } } }, { "sample_id": "400-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "27.9(3)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7371, "char_end": 7378, "end_exclusive": true, "literal_sha256": "529cef1d5dc70f364d3d411ca3af700905a09dabc9616360014c0d605aed1403" } }, "Sc": { "raw_value": "21.6(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7381, "char_end": 7388, "end_exclusive": true, "literal_sha256": "d203409e4195bc4e374116461dd3d512b9a3610603680885ea0a277ccc7735db" } }, "Ti": { "raw_value": "25.3(3)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7391, "char_end": 7398, "end_exclusive": true, "literal_sha256": "250fb449d4a096824019e0889ccd7d64dd9f337744282166ce499ef1b18ff627" } }, "Zr": { "raw_value": "25.2(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7401, "char_end": 7408, "end_exclusive": true, "literal_sha256": "2621f56a878b40948f6415cf13ff2d328a4e776ee9082a438baca89e9072123b" } }, "lattice_a": { "raw_value": "3.308(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7490, "char_end": 7498, "end_exclusive": true, "literal_sha256": "fd6f46d95e86ce95a1e90ad80e84ae33ae7fa578a9a8bd13c90dc616faf4c94b" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2024-table-1", "literal": null } } }, { "sample_id": "400-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "22.1(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7518, "char_end": 7525, "end_exclusive": true, "literal_sha256": "8f1c9c74efe35bdb4a9b041ded4be4359e761ba22ef847c84152292cbf931185" } }, "Sc": { "raw_value": "32.3(9)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7528, "char_end": 7535, "end_exclusive": true, "literal_sha256": "e2f691dcc42bf7a3ed5df13df203308036e3993a02d2e12d3f3cb90e5ad26d4b" } }, "Ti": { "raw_value": "21.3(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7538, "char_end": 7545, "end_exclusive": true, "literal_sha256": "c8cababf8d7c8238bae5aa858020751a5169e008a64e320aded017772bd572c8" } }, "Zr": { "raw_value": "24.2(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7548, "char_end": 7555, "end_exclusive": true, "literal_sha256": "1ef3a007137201ac53a24c26720c0184ce47714ae37b4a1045af697851a64aa5" } }, "lattice_a": { "raw_value": "3.252(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7562, "char_end": 7570, "end_exclusive": true, "literal_sha256": "99c2f5b7e1cb49556e74da58cd58a72fbd157f6a4ca8ac0807536b0388831292" } }, "lattice_c": { "raw_value": "5.131(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7574, "char_end": 7582, "end_exclusive": true, "literal_sha256": "0a25d135ec84b3aebc9d3e7bc9f4d20c98426c8522ec1c47759b43852cf70b13" } } } }, { "sample_id": "600-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "29.1(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7625, "char_end": 7632, "end_exclusive": true, "literal_sha256": "c6472f0524ca8f27833d3ea8965f7962cbeb30658d271c5f829fd234bc9a2d5f" } }, "Sc": { "raw_value": "19.1(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7635, "char_end": 7642, "end_exclusive": true, "literal_sha256": "b54a705ce3d0bf8151f16f1ddae9cf0e3bacf0ca635ebff2128aad474f4c19f9" } }, "Ti": { "raw_value": "29.8(9)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7645, "char_end": 7652, "end_exclusive": true, "literal_sha256": "d7caa431a1b8a9855a8acf6fa125b290424e610ec1fb3e9a94f29a1e68ae8f0b" } }, "Zr": { "raw_value": "22(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7655, "char_end": 7660, "end_exclusive": true, "literal_sha256": "6be0380aebff82b6c1860c3516b30ceae7de2142ddb1f6830f883fb44eca2b6b" } }, "lattice_a": { "raw_value": "3.314(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7675, "char_end": 7683, "end_exclusive": true, "literal_sha256": "0840408bd47db797e12ffbac4f7caea988717b912efba908ac10ec644378ca9a" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2024-table-1", "literal": null } } }, { "sample_id": "600-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "18.0(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7704, "char_end": 7711, "end_exclusive": true, "literal_sha256": "6eebd4a18f073b668f1e83335698a4bd6c60d97bb6d094e4b051127feb0799a2" } }, "Sc": { "raw_value": "32(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7714, "char_end": 7719, "end_exclusive": true, "literal_sha256": "e39fb2f621ed462f3996448a0a08fc8118cf70a8f8e9f6479f09d2482a4f11ec" } }, "Ti": { "raw_value": "19(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7722, "char_end": 7727, "end_exclusive": true, "literal_sha256": "f83127a8e6d0718f64dcc4205b0bea5e3a61d0c43c41f0c19bfc0a8de77deeb3" } }, "Zr": { "raw_value": "30.8(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7730, "char_end": 7737, "end_exclusive": true, "literal_sha256": "7821ffb05f2f68ca72dfb6d8fcc77709fbe4343eda7e2b9368df7e92f3e96210" } }, "lattice_a": { "raw_value": "3.254(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7747, "char_end": 7755, "end_exclusive": true, "literal_sha256": "7a66949970122f442169e7b1fffc32291680a07ead4bcb2f052fde476d3fd021" } }, "lattice_c": { "raw_value": "5.133(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7759, "char_end": 7767, "end_exclusive": true, "literal_sha256": "051ab60d742bde386293fdc8fff4101e4c4b9f1bf4528cc4d24f4f61cc2310f6" } } } }, { "sample_id": "800-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "33(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7790, "char_end": 7795, "end_exclusive": true, "literal_sha256": "81eee87f414106096eb89581a96e2944c89194b34c90a8edb49682ed04f6fd40" } }, "Sc": { "raw_value": "15(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7798, "char_end": 7803, "end_exclusive": true, "literal_sha256": "2adbcca3f20bcd0d8898babcbd83ef1025c356333d22281aec4a015faca4ace8" } }, "Ti": { "raw_value": "32(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7806, "char_end": 7811, "end_exclusive": true, "literal_sha256": "e39fb2f621ed462f3996448a0a08fc8118cf70a8f8e9f6479f09d2482a4f11ec" } }, "Zr": { "raw_value": "20(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7814, "char_end": 7819, "end_exclusive": true, "literal_sha256": "2ef5b2a683ef9b8fc67549441d2392b2b5ea4f986a7735251e723172fe0a130c" } }, "lattice_a": { "raw_value": "3.325(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7838, "char_end": 7846, "end_exclusive": true, "literal_sha256": "61a78108ddd66c790903d43769752025f36e7761447fd7b4501fc604608da51d" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2024-table-1", "literal": null } } }, { "sample_id": "800-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "13(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7867, "char_end": 7872, "end_exclusive": true, "literal_sha256": "304cc7fa8b157c686edf378caedbcac5b113ea7405f812ea7eca1467abd32719" } }, "Sc": { "raw_value": "39.1(9)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7875, "char_end": 7882, "end_exclusive": true, "literal_sha256": "d1f3cabc1e6338f15edff376425a54a2a8dd1e6c1f488fd1306ff185c2d3e88c" } }, "Ti": { "raw_value": "15.1(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7885, "char_end": 7892, "end_exclusive": true, "literal_sha256": "a6861039adaab2f1319f041e60b0698e264e5c79c5e4479b61f9aa1d05517da7" } }, "Zr": { "raw_value": "32.6(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7895, "char_end": 7902, "end_exclusive": true, "literal_sha256": "3f545672520785bc77c9a0c55ad8e9f4475bc4bbc3c47281f60fa2e4734e7e7c" } }, "lattice_a": { "raw_value": "3.252(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7910, "char_end": 7918, "end_exclusive": true, "literal_sha256": "e11b7b20f314b027cf483b88c4cd5611efef47928fe00ad459ff919583f761e7" } }, "lattice_c": { "raw_value": "5.138(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7922, "char_end": 7930, "end_exclusive": true, "literal_sha256": "a7ef6a7124a9733c2ca5ca1502bca2d593e652c24f5893e2cd06c6c07f28e283" } } } }, { "sample_id": "1000-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "39.0(8)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7949, "char_end": 7956, "end_exclusive": true, "literal_sha256": "c80081a51d990ed6ffe9e1a4a67c87ddf3ff22364fa718ed1cb1477681f2e8c7" } }, "Sc": { "raw_value": "4.2(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7959, "char_end": 7965, "end_exclusive": true, "literal_sha256": "81fe04cfde7a446a596137bd012a793493ac8538cd1e5c1b881f9f147cec5731" } }, "Ti": { "raw_value": "38.0(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7968, "char_end": 7975, "end_exclusive": true, "literal_sha256": "c81a1cc57cb7e6ba8893249224f5b6345f772225b1aa18e1f163d6b20402cffb" } }, "Zr": { "raw_value": "18.9(8)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 7978, "char_end": 7985, "end_exclusive": true, "literal_sha256": "d618920b6a3886a6dc36ec3ce5ea94b4824b4143ef77b78e422b47a0f674328d" } }, "lattice_a": { "raw_value": "3.360(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8068, "char_end": 8076, "end_exclusive": true, "literal_sha256": "fcad745081564fcb1bdfb787d434b3f679561d40fc14d9ed4ceecadb49ee7ab2" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2024-table-1", "literal": null } } }, { "sample_id": "1000-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "2.6(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8098, "char_end": 8104, "end_exclusive": true, "literal_sha256": "e3eff9acaa19a797e4fff9731cfea8376b6e502f06eb2dad46efdb0f9304c717" } }, "Sc": { "raw_value": "56(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8107, "char_end": 8112, "end_exclusive": true, "literal_sha256": "e1c7b7b22af621a9a4fdc78b6e78eed350abaf03eed93441fb16578701628c1a" } }, "Ti": { "raw_value": "7.3(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8115, "char_end": 8121, "end_exclusive": true, "literal_sha256": "5e2eb37ae0bbadb4f2d00474e45672dd517eaa108ce3a0aa96f83eccedcbdf57" } }, "Zr": { "raw_value": "34.1(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8124, "char_end": 8131, "end_exclusive": true, "literal_sha256": "6ecddb758dccba00da9cc05989b7e4caabbf7e2025ba3395b6285f4964f468ba" } }, "lattice_a": { "raw_value": "3.260(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8140, "char_end": 8148, "end_exclusive": true, "literal_sha256": "473a6449fecdf5a965a0e5a3062490eca624a68fe7120815f43a5780383daddc" } }, "lattice_c": { "raw_value": "5.141(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2024-table-1", "literal": { "char_start": 8152, "char_end": 8160, "end_exclusive": true, "literal_sha256": "d74b2fcb59daed6f45ec58056372ed6202763a09b25125493509c3ad90d9dbb8" } } } } ] }, "phase_table_2023": { "source_id": "2023", "source_locator_id": "2023-table-1", "label": "2023 Table 1: phase compositions, volume fractions and VEC", "composition_unit": "not_printed_in_table", "composition_scope": "Separate 2023 source rows; chemical coefficients, lattice parameters, SEM volume fractions and source-derived VEC are retained independently.", "columns": [ "Nb", "Sc", "Ti", "Zr", "lattice_a", "lattice_c", "volume_percent", "vec" ], "rows": [ { "sample_id": "as-cast", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "26.6(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13364, "char_end": 13371, "end_exclusive": true, "literal_sha256": "d8051c95bf8c43986ba2d21033b4786deab7de53a842b42392834bfcd74635e5" } }, "Sc": { "raw_value": "22.3(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13374, "char_end": 13381, "end_exclusive": true, "literal_sha256": "f457150d216d2f38c16db4da5ea1b693c57233663edf8faad88fc13198e9a320" } }, "Ti": { "raw_value": "25.5(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13384, "char_end": 13391, "end_exclusive": true, "literal_sha256": "4e5b03aba5765ec4d26fc81a848af3cb11110144a4e14622fd6b7f8b4114b0bc" } }, "Zr": { "raw_value": "25.6(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13394, "char_end": 13401, "end_exclusive": true, "literal_sha256": "640c3a92c10c884d74cbb911756b7155e0e8226a2639553991885f7dd2d5e64d" } }, "lattice_a": { "raw_value": "3.359(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13414, "char_end": 13422, "end_exclusive": true, "literal_sha256": "99c19934e9016190685dce3d2b09d8ef7de6257c9915fb5453276fb29d89a17d" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2023-table-1", "literal": null }, "volume_percent": { "raw_value": "57", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13404, "char_end": 13406, "end_exclusive": true, "literal_sha256": "c837649cce43f2729138e72cc315207057ac82599a59be72765a477f22d14a54" } }, "vec": { "raw_value": "4.04", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13437, "char_end": 13441, "end_exclusive": true, "literal_sha256": "d74586442881c00892adb2190aafaa58c4f8efa7a9425325c3835e452dc5a4b8" } } } }, { "sample_id": "as-cast", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "21.3(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13466, "char_end": 13473, "end_exclusive": true, "literal_sha256": "33aa22d3b619d14333f80b0dd6f35e05e1ac1bfdf7625cd7ff2c50dee0beeff2" } }, "Sc": { "raw_value": "30(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13476, "char_end": 13481, "end_exclusive": true, "literal_sha256": "586fb8e5e81b7da643a8997d65b5a057e71f50e059fe266b19bd130c7f5cfa41" } }, "Ti": { "raw_value": "23.0(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13484, "char_end": 13491, "end_exclusive": true, "literal_sha256": "13f460e831f2d7882795fba6bfabe8ab20364a57b36b58e06560fb75abf6ff85" } }, "Zr": { "raw_value": "25.8(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13494, "char_end": 13501, "end_exclusive": true, "literal_sha256": "66b155403270a3cbab1b8b64ae284aeda2d06faca6d9e8038e62e5eaede68ac0" } }, "lattice_a": { "raw_value": "3.262(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13516, "char_end": 13524, "end_exclusive": true, "literal_sha256": "2d0b6a5973478fecb2b5c825dd504615ba328833f856916009a55c6cfe9108fd" } }, "lattice_c": { "raw_value": "5.152(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13528, "char_end": 13536, "end_exclusive": true, "literal_sha256": "8ea49a280e97a6bb4c4ded2270eb4078b2327fb6637d4a9630dc4a9c2fdb51a8" } }, "volume_percent": { "raw_value": "43", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13506, "char_end": 13508, "end_exclusive": true, "literal_sha256": "44cb730c420480a0477b505ae68af508fb90f96cf0ec54c6ad16949dd427f13a" } }, "vec": { "raw_value": "3.91", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13539, "char_end": 13543, "end_exclusive": true, "literal_sha256": "81f6a8bd7b04cfc499702103012991ebd808493c006e224b180b447f56d981aa" } } } }, { "sample_id": "400-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "27.9(3)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13562, "char_end": 13569, "end_exclusive": true, "literal_sha256": "529cef1d5dc70f364d3d411ca3af700905a09dabc9616360014c0d605aed1403" } }, "Sc": { "raw_value": "21.6(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13572, "char_end": 13579, "end_exclusive": true, "literal_sha256": "d203409e4195bc4e374116461dd3d512b9a3610603680885ea0a277ccc7735db" } }, "Ti": { "raw_value": "25.3(3)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13582, "char_end": 13589, "end_exclusive": true, "literal_sha256": "250fb449d4a096824019e0889ccd7d64dd9f337744282166ce499ef1b18ff627" } }, "Zr": { "raw_value": "25.2(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13592, "char_end": 13599, "end_exclusive": true, "literal_sha256": "2621f56a878b40948f6415cf13ff2d328a4e776ee9082a438baca89e9072123b" } }, "lattice_a": { "raw_value": "3.308(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13612, "char_end": 13620, "end_exclusive": true, "literal_sha256": "fd6f46d95e86ce95a1e90ad80e84ae33ae7fa578a9a8bd13c90dc616faf4c94b" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2023-table-1", "literal": null }, "volume_percent": { "raw_value": "57", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13602, "char_end": 13604, "end_exclusive": true, "literal_sha256": "c837649cce43f2729138e72cc315207057ac82599a59be72765a477f22d14a54" } }, "vec": { "raw_value": "4.06", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13635, "char_end": 13639, "end_exclusive": true, "literal_sha256": "4f121e31acb816cf54b3566736265dea5d1ce3f73c60ac6cd7bc359e4c3dbb99" } } } }, { "sample_id": "400-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "22.1(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13664, "char_end": 13671, "end_exclusive": true, "literal_sha256": "8f1c9c74efe35bdb4a9b041ded4be4359e761ba22ef847c84152292cbf931185" } }, "Sc": { "raw_value": "32.3(9)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13674, "char_end": 13681, "end_exclusive": true, "literal_sha256": "e2f691dcc42bf7a3ed5df13df203308036e3993a02d2e12d3f3cb90e5ad26d4b" } }, "Ti": { "raw_value": "21.3(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13684, "char_end": 13691, "end_exclusive": true, "literal_sha256": "c8cababf8d7c8238bae5aa858020751a5169e008a64e320aded017772bd572c8" } }, "Zr": { "raw_value": "24.2(2)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13694, "char_end": 13701, "end_exclusive": true, "literal_sha256": "1ef3a007137201ac53a24c26720c0184ce47714ae37b4a1045af697851a64aa5" } }, "lattice_a": { "raw_value": "3.252(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13714, "char_end": 13722, "end_exclusive": true, "literal_sha256": "99c2f5b7e1cb49556e74da58cd58a72fbd157f6a4ca8ac0807536b0388831292" } }, "lattice_c": { "raw_value": "5.131(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13726, "char_end": 13734, "end_exclusive": true, "literal_sha256": "0a25d135ec84b3aebc9d3e7bc9f4d20c98426c8522ec1c47759b43852cf70b13" } }, "volume_percent": { "raw_value": "43", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13704, "char_end": 13706, "end_exclusive": true, "literal_sha256": "44cb730c420480a0477b505ae68af508fb90f96cf0ec54c6ad16949dd427f13a" } }, "vec": { "raw_value": "3.90", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13737, "char_end": 13741, "end_exclusive": true, "literal_sha256": "ec2bb902368079355b2fdba07ded8a6dc96aad06f621412d1e746bd9539ae889" } } } }, { "sample_id": "800-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "33(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13760, "char_end": 13765, "end_exclusive": true, "literal_sha256": "81eee87f414106096eb89581a96e2944c89194b34c90a8edb49682ed04f6fd40" } }, "Sc": { "raw_value": "15(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13768, "char_end": 13773, "end_exclusive": true, "literal_sha256": "2adbcca3f20bcd0d8898babcbd83ef1025c356333d22281aec4a015faca4ace8" } }, "Ti": { "raw_value": "32(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13776, "char_end": 13781, "end_exclusive": true, "literal_sha256": "e39fb2f621ed462f3996448a0a08fc8118cf70a8f8e9f6479f09d2482a4f11ec" } }, "Zr": { "raw_value": "20(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13784, "char_end": 13789, "end_exclusive": true, "literal_sha256": "2ef5b2a683ef9b8fc67549441d2392b2b5ea4f986a7735251e723172fe0a130c" } }, "lattice_a": { "raw_value": "3.325(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13810, "char_end": 13818, "end_exclusive": true, "literal_sha256": "61a78108ddd66c790903d43769752025f36e7761447fd7b4501fc604608da51d" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2023-table-1", "literal": null }, "volume_percent": { "raw_value": "50", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13800, "char_end": 13802, "end_exclusive": true, "literal_sha256": "1a6562590ef19d1045d06c4055742d38288e9e6dcd71ccde5cee80f1d5a774eb" } }, "vec": { "raw_value": "4.18", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13833, "char_end": 13837, "end_exclusive": true, "literal_sha256": "c0996957415530d5188d60ee58f48e0eb1888825429d362e702977f6f82b2889" } } } }, { "sample_id": "800-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "13(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13862, "char_end": 13867, "end_exclusive": true, "literal_sha256": "304cc7fa8b157c686edf378caedbcac5b113ea7405f812ea7eca1467abd32719" } }, "Sc": { "raw_value": "39.1(9)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13870, "char_end": 13877, "end_exclusive": true, "literal_sha256": "d1f3cabc1e6338f15edff376425a54a2a8dd1e6c1f488fd1306ff185c2d3e88c" } }, "Ti": { "raw_value": "15.1(4)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13880, "char_end": 13887, "end_exclusive": true, "literal_sha256": "a6861039adaab2f1319f041e60b0698e264e5c79c5e4479b61f9aa1d05517da7" } }, "Zr": { "raw_value": "32.6(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13890, "char_end": 13897, "end_exclusive": true, "literal_sha256": "3f545672520785bc77c9a0c55ad8e9f4475bc4bbc3c47281f60fa2e4734e7e7c" } }, "lattice_a": { "raw_value": "3.252(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13912, "char_end": 13920, "end_exclusive": true, "literal_sha256": "e11b7b20f314b027cf483b88c4cd5611efef47928fe00ad459ff919583f761e7" } }, "lattice_c": { "raw_value": "5.138(3)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13924, "char_end": 13932, "end_exclusive": true, "literal_sha256": "a7ef6a7124a9733c2ca5ca1502bca2d593e652c24f5893e2cd06c6c07f28e283" } }, "volume_percent": { "raw_value": "50", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13902, "char_end": 13904, "end_exclusive": true, "literal_sha256": "1a6562590ef19d1045d06c4055742d38288e9e6dcd71ccde5cee80f1d5a774eb" } }, "vec": { "raw_value": "3.74", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13935, "char_end": 13939, "end_exclusive": true, "literal_sha256": "a088fac4d44900acecd167516201b06b424353b803a7898f67d88167c54946b3" } } } }, { "sample_id": "1000-c", "phase_label": "bcc", "cells": { "Nb": { "raw_value": "39.0(8)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13958, "char_end": 13965, "end_exclusive": true, "literal_sha256": "c80081a51d990ed6ffe9e1a4a67c87ddf3ff22364fa718ed1cb1477681f2e8c7" } }, "Sc": { "raw_value": "4.2(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13968, "char_end": 13974, "end_exclusive": true, "literal_sha256": "81fe04cfde7a446a596137bd012a793493ac8538cd1e5c1b881f9f147cec5731" } }, "Ti": { "raw_value": "38.0(6)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13977, "char_end": 13984, "end_exclusive": true, "literal_sha256": "c81a1cc57cb7e6ba8893249224f5b6345f772225b1aa18e1f163d6b20402cffb" } }, "Zr": { "raw_value": "18.9(8)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13987, "char_end": 13994, "end_exclusive": true, "literal_sha256": "d618920b6a3886a6dc36ec3ce5ea94b4824b4143ef77b78e422b47a0f674328d" } }, "lattice_a": { "raw_value": "3.360(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14008, "char_end": 14016, "end_exclusive": true, "literal_sha256": "fcad745081564fcb1bdfb787d434b3f679561d40fc14d9ed4ceecadb49ee7ab2" } }, "lattice_c": { "raw_value": null, "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "not_listed_in_source_row", "source_locator_id": "2023-table-1", "literal": null }, "volume_percent": { "raw_value": "50", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13998, "char_end": 14000, "end_exclusive": true, "literal_sha256": "1a6562590ef19d1045d06c4055742d38288e9e6dcd71ccde5cee80f1d5a774eb" } }, "vec": { "raw_value": "4.35", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14031, "char_end": 14035, "end_exclusive": true, "literal_sha256": "6d98ea24827f5a019110f671bdab1596d35800c5ee5557d5af709ed3eab75aea" } } } }, { "sample_id": "1000-c", "phase_label": "hcp", "cells": { "Nb": { "raw_value": "2.6(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14060, "char_end": 14066, "end_exclusive": true, "literal_sha256": "e3eff9acaa19a797e4fff9731cfea8376b6e502f06eb2dad46efdb0f9304c717" } }, "Sc": { "raw_value": "56(1)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14069, "char_end": 14074, "end_exclusive": true, "literal_sha256": "e1c7b7b22af621a9a4fdc78b6e78eed350abaf03eed93441fb16578701628c1a" } }, "Ti": { "raw_value": "7.3(7)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14077, "char_end": 14083, "end_exclusive": true, "literal_sha256": "5e2eb37ae0bbadb4f2d00474e45672dd517eaa108ce3a0aa96f83eccedcbdf57" } }, "Zr": { "raw_value": "34.1(5)", "raw_unit": null, "normalized_value": null, "role": "source_composition_coefficient_with_printed_uncertainty", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14086, "char_end": 14093, "end_exclusive": true, "literal_sha256": "6ecddb758dccba00da9cc05989b7e4caabbf7e2025ba3395b6285f4964f468ba" } }, "lattice_a": { "raw_value": "3.260(1)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14110, "char_end": 14118, "end_exclusive": true, "literal_sha256": "473a6449fecdf5a965a0e5a3062490eca624a68fe7120815f43a5780383daddc" } }, "lattice_c": { "raw_value": "5.141(2)", "raw_unit": "Å", "normalized_value": null, "role": "source_xrd_lattice_parameter", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14122, "char_end": 14130, "end_exclusive": true, "literal_sha256": "d74b2fcb59daed6f45ec58056372ed6202763a09b25125493509c3ad90d9dbb8" } }, "volume_percent": { "raw_value": "50", "raw_unit": "vol.%", "normalized_value": null, "role": "source_sem_phase_volume_fraction", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14100, "char_end": 14102, "end_exclusive": true, "literal_sha256": "1a6562590ef19d1045d06c4055742d38288e9e6dcd71ccde5cee80f1d5a774eb" } }, "vec": { "raw_value": "3.47", "raw_unit": null, "normalized_value": null, "role": "source_composition_derived_valence_electron_concentration", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14133, "char_end": 14137, "end_exclusive": true, "literal_sha256": "9c56c14ca32db1092d366ae29f80dedcbd8960c037c56c85c237ca2f214ed88a" } } } } ] }, "parameter_table": { "source_id": "2024", "source_locator_id": "2024-table-2", "label": "2024 Table 2: superconducting parameters and hardness", "columns": [ { "field": "tc_k", "label": "Tabulated Tc", "raw_unit": "K", "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "unit_basis": "printed_table_header" }, { "field": "gamma_el", "label": "γel", "raw_unit": "mJ/mol·K2", "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "unit_basis": "printed_table_header" }, { "field": "beta", "label": "β", "raw_unit": "mJ/mol·K4", "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "unit_basis": "printed_table_header" }, { "field": "hc1_zero_mt", "label": "μ0 Hc1(0)", "raw_unit": "mT", "role": "gl_fit_extrapolation_from_initial_magnetization", "unit_basis": "printed_table_header" }, { "field": "hc2_m_zero_t", "label": "μ0 Hc2ᴹ(0)", "raw_unit": "T", "role": "whh_fit_from_magnetization_transition_onset", "unit_basis": "printed_table_header" }, { "field": "maki_m", "label": "αMᴹ", "raw_unit": null, "role": "whh_fit_maki_parameter_from_magnetization", "unit_basis": "source_parameter_symbol_without_printed_unit" }, { "field": "hc2_rho_zero_t", "label": "μ0 Hc2ρ(0)", "raw_unit": "T", "role": "whh_fit_from_resistivity_transition_onset", "unit_basis": "printed_table_header" }, { "field": "maki_rho", "label": "αMρ", "raw_unit": null, "role": "whh_fit_maki_parameter_from_resistivity", "unit_basis": "source_parameter_symbol_without_printed_unit" }, { "field": "xi_m_zero_nm", "label": "ξGLᴹ(0)", "raw_unit": "nm", "role": "gl_coherence_length_derived_from_hc2_m", "unit_basis": "printed_table_header" }, { "field": "lambda_m_zero_nm", "label": "λGLᴹ(0)", "raw_unit": "nm", "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "unit_basis": "printed_table_header" }, { "field": "kappa_m", "label": "κGLᴹ", "raw_unit": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "unit_basis": "source_parameter_symbol_without_printed_unit" }, { "field": "xi_rho_zero_nm", "label": "ξGLρ(0)", "raw_unit": "nm", "role": "gl_coherence_length_derived_from_hc2_rho", "unit_basis": "printed_table_header" }, { "field": "lambda_rho_zero_nm", "label": "λGLρ(0)", "raw_unit": "nm", "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "unit_basis": "printed_table_header" }, { "field": "kappa_rho", "label": "κGLρ", "raw_unit": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "unit_basis": "source_parameter_symbol_without_printed_unit" }, { "field": "hardness_hv", "label": "Vickers hardness", "raw_unit": "HV", "role": "indentation_measurement_2_94_n_for_10_s", "unit_basis": "printed_table_header" } ], "rows": [ { "sample_id": "as-cast", "cells": { "tc_k": { "raw_value": "8.11", "raw_unit": "K", "normalized_value": null, "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19161, "char_end": 19165, "end_exclusive": true, "literal_sha256": "7e3f3dc553debd7eb597b8c8488d8f23da26e4d35eecc681b0e9d43b4d7bf70b" } }, "gamma_el": { "raw_value": "6.47", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19234, "char_end": 19238, "end_exclusive": true, "literal_sha256": "16eb21a9f8fbf2567126cb7cac160fd84b2fdc6a0b8cf901889fd508359d94a2" } }, "beta": { "raw_value": "0.150", "raw_unit": "mJ/mol·K4", "normalized_value": null, "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19306, "char_end": 19311, "end_exclusive": true, "literal_sha256": "1835a0a912dd6d9a4fcdf07b248d8cec881ea4f784fcc6af51dd36e5e0744ee5" } }, "hc1_zero_mt": { "raw_value": "29.1", "raw_unit": "mT", "normalized_value": null, "role": "gl_fit_extrapolation_from_initial_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19380, "char_end": 19384, "end_exclusive": true, "literal_sha256": "b182ecbd4641071bf74ba85feb2ae1935d0e96bb1d1fe557a61f0eae6f9ed9bb" } }, "hc2_m_zero_t": { "raw_value": "13.1", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_magnetization_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19472, "char_end": 19476, "end_exclusive": true, "literal_sha256": "2059b54a6dd3de9a703ec83a9df39125df5f9eb6ed19f609c6c7a7725ba9ecf8" } }, "maki_m": { "raw_value": "1.7", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19570, "char_end": 19573, "end_exclusive": true, "literal_sha256": "8f65223004a75f44404f485a1e84090699acef51f39de9411d6d9b377ae859a5" } }, "hc2_rho_zero_t": { "raw_value": "12.8", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_resistivity_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19662, "char_end": 19666, "end_exclusive": true, "literal_sha256": "1d377636299fcb9cf354e6ca7ca109bbbe5d121109a4af666eca82c2dfdff184" } }, "maki_rho": { "raw_value": "1.7", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_resistivity", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19736, "char_end": 19739, "end_exclusive": true, "literal_sha256": "8f65223004a75f44404f485a1e84090699acef51f39de9411d6d9b377ae859a5" } }, "xi_m_zero_nm": { "raw_value": "5.0", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19825, "char_end": 19828, "end_exclusive": true, "literal_sha256": "a19a1584344c1f3783bff51524a5a4b86f2cc09356c9dbfb6af9cd236e314362" } }, "lambda_m_zero_nm": { "raw_value": "137", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19913, "char_end": 19916, "end_exclusive": true, "literal_sha256": "d80eae6e96d148b3b2abbbc6760077b66c4ea071f847dab573d507a32c4d99a5" } }, "kappa_m": { "raw_value": "27", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20008, "char_end": 20010, "end_exclusive": true, "literal_sha256": "670671cd97404156226e507973f2ab8330d3022ca96e0c93bdbdb320c41adcaf" } }, "xi_rho_zero_nm": { "raw_value": "5.1", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20096, "char_end": 20099, "end_exclusive": true, "literal_sha256": "77065cda8fe1551871ba934cfef4df0f9e8a5f7fb63909b25bf0ccebbe807e18" } }, "lambda_rho_zero_nm": { "raw_value": "137", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20168, "char_end": 20171, "end_exclusive": true, "literal_sha256": "d80eae6e96d148b3b2abbbc6760077b66c4ea071f847dab573d507a32c4d99a5" } }, "kappa_rho": { "raw_value": "27", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20263, "char_end": 20265, "end_exclusive": true, "literal_sha256": "670671cd97404156226e507973f2ab8330d3022ca96e0c93bdbdb320c41adcaf" } }, "hardness_hv": { "raw_value": "336(1)", "raw_unit": "HV", "normalized_value": null, "role": "indentation_measurement_2_94_n_for_10_s", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20332, "char_end": 20338, "end_exclusive": true, "literal_sha256": "0cd935dd6725223fec0d9060e8360a791958cd494d1da6c362b20ad19c07d294" } } } }, { "sample_id": "400-c", "cells": { "tc_k": { "raw_value": "8.71", "raw_unit": "K", "normalized_value": null, "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19168, "char_end": 19172, "end_exclusive": true, "literal_sha256": "e3bd5e42d798e2791b549cbda52536076b6a87261ec69542ca39866afeefeb47" } }, "gamma_el": { "raw_value": "6.79", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19241, "char_end": 19245, "end_exclusive": true, "literal_sha256": "7c730065f11c16c622827efa7a7b0cf1da38312481685e659b6ff4c0c1dccadd" } }, "beta": { "raw_value": "0.127", "raw_unit": "mJ/mol·K4", "normalized_value": null, "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19312, "char_end": 19317, "end_exclusive": true, "literal_sha256": "c13097d9841efebb159b95aef88717813f7f0e0933aca1506c22aeebfb2df477" } }, "hc1_zero_mt": { "raw_value": "32.9", "raw_unit": "mT", "normalized_value": null, "role": "gl_fit_extrapolation_from_initial_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19387, "char_end": 19391, "end_exclusive": true, "literal_sha256": "83bcafb1853ce1c148c88f4655b887d96b778fa1ddb18ef9a8164bba03c6859d" } }, "hc2_m_zero_t": { "raw_value": "14.1", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_magnetization_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19480, "char_end": 19484, "end_exclusive": true, "literal_sha256": "fca61c35cab065b1582a6759a0e4f3177773c76586c38bc33a4da61b3599bea7" } }, "maki_m": { "raw_value": "1.8", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19577, "char_end": 19580, "end_exclusive": true, "literal_sha256": "a97b042d7bd59d92a46e8ab17f7dff7326067c74b938e6f6daabf1768932330d" } }, "hc2_rho_zero_t": { "raw_value": "12.7", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_resistivity_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19669, "char_end": 19673, "end_exclusive": true, "literal_sha256": "eda90e5b66a4d492e1140f856caae1b71e55f1cbb34e6fda5d2f5921e3925d8e" } }, "maki_rho": { "raw_value": "1.9", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_resistivity", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19743, "char_end": 19746, "end_exclusive": true, "literal_sha256": "eca06fdd26e513a7b8510c86602285041a916de5491de13373d94fe0d7e04737" } }, "xi_m_zero_nm": { "raw_value": "4.8", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19832, "char_end": 19835, "end_exclusive": true, "literal_sha256": "9c7f38a9ac4f5de592be486948ac944aff688f914e3b74e6917c7fe4715a561e" } }, "lambda_m_zero_nm": { "raw_value": "128", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19920, "char_end": 19923, "end_exclusive": true, "literal_sha256": "2747b7c718564ba5f066f0523b03e17f6a496b06851333d2d59ab6d863225848" } }, "kappa_m": { "raw_value": "27", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20015, "char_end": 20017, "end_exclusive": true, "literal_sha256": "670671cd97404156226e507973f2ab8330d3022ca96e0c93bdbdb320c41adcaf" } }, "xi_rho_zero_nm": { "raw_value": "5.1", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20103, "char_end": 20106, "end_exclusive": true, "literal_sha256": "77065cda8fe1551871ba934cfef4df0f9e8a5f7fb63909b25bf0ccebbe807e18" } }, "lambda_rho_zero_nm": { "raw_value": "127", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20175, "char_end": 20178, "end_exclusive": true, "literal_sha256": "922c7954216ccfe7a61def609305ce1dc7c67e225f873f256d30d7a8ee4f404c" } }, "kappa_rho": { "raw_value": "25", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20270, "char_end": 20272, "end_exclusive": true, "literal_sha256": "b7a56873cd771f2c446d369b649430b65a756ba278ff97ec81bb6f55b2e73569" } }, "hardness_hv": { "raw_value": "345(4)", "raw_unit": "HV", "normalized_value": null, "role": "indentation_measurement_2_94_n_for_10_s", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20339, "char_end": 20345, "end_exclusive": true, "literal_sha256": "68d273b5adc3aac0abf29b511e4d6a53f997c29b3b696caeddd208af3cb8d75c" } } } }, { "sample_id": "600-c", "cells": { "tc_k": { "raw_value": "9.36", "raw_unit": "K", "normalized_value": null, "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19176, "char_end": 19180, "end_exclusive": true, "literal_sha256": "b362c89d157c62b424cc66747e8f815282e9c5d3b851ae7db3dd19cfa3f65ef5" } }, "gamma_el": { "raw_value": "5.77", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19250, "char_end": 19254, "end_exclusive": true, "literal_sha256": "ad9380b77b69c91afa21f3ffe1942661cf3ea7fdb2987d6e27bb55bff3943225" } }, "beta": { "raw_value": "0.127", "raw_unit": "mJ/mol·K4", "normalized_value": null, "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19322, "char_end": 19327, "end_exclusive": true, "literal_sha256": "c13097d9841efebb159b95aef88717813f7f0e0933aca1506c22aeebfb2df477" } }, "hc1_zero_mt": { "raw_value": "22.9", "raw_unit": "mT", "normalized_value": null, "role": "gl_fit_extrapolation_from_initial_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19396, "char_end": 19400, "end_exclusive": true, "literal_sha256": "8ab4dab64f0173d7da9b27e0211d8646a0d1fa965cf852ef87e7387f0a28383c" } }, "hc2_m_zero_t": { "raw_value": "14.6", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_magnetization_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19488, "char_end": 19492, "end_exclusive": true, "literal_sha256": "d28f3edfe24e49c37c02bef18f385b1522d20550186f445a397d4a0a006c8b79" } }, "maki_m": { "raw_value": "1.4", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19585, "char_end": 19588, "end_exclusive": true, "literal_sha256": "1a948f1b4374f4e3f02501c7feb43784021718a93c1ed5f9f19adf357bb2d20e" } }, "hc2_rho_zero_t": { "raw_value": "14.5", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_resistivity_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19678, "char_end": 19682, "end_exclusive": true, "literal_sha256": "6978e2340a8503590a60b7d19aae46c4ea02a62986b91628d06ae0e35b011e0d" } }, "maki_rho": { "raw_value": "1.4", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_resistivity", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19751, "char_end": 19754, "end_exclusive": true, "literal_sha256": "1a948f1b4374f4e3f02501c7feb43784021718a93c1ed5f9f19adf357bb2d20e" } }, "xi_m_zero_nm": { "raw_value": "4.8", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19841, "char_end": 19844, "end_exclusive": true, "literal_sha256": "9c7f38a9ac4f5de592be486948ac944aff688f914e3b74e6917c7fe4715a561e" } }, "lambda_m_zero_nm": { "raw_value": "159", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19929, "char_end": 19932, "end_exclusive": true, "literal_sha256": "ff2ccb6ba423d356bd549ed4bfb76e96976a0dcde05a09996a1cdb9f83422ec4" } }, "kappa_m": { "raw_value": "33", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20024, "char_end": 20026, "end_exclusive": true, "literal_sha256": "c6f3ac57944a531490cd39902d0f777715fd005efac9a30622d5f5205e7f6894" } }, "xi_rho_zero_nm": { "raw_value": "4.8", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20112, "char_end": 20115, "end_exclusive": true, "literal_sha256": "9c7f38a9ac4f5de592be486948ac944aff688f914e3b74e6917c7fe4715a561e" } }, "lambda_rho_zero_nm": { "raw_value": "159", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20184, "char_end": 20187, "end_exclusive": true, "literal_sha256": "ff2ccb6ba423d356bd549ed4bfb76e96976a0dcde05a09996a1cdb9f83422ec4" } }, "kappa_rho": { "raw_value": "33", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20279, "char_end": 20281, "end_exclusive": true, "literal_sha256": "c6f3ac57944a531490cd39902d0f777715fd005efac9a30622d5f5205e7f6894" } }, "hardness_hv": { "raw_value": "264(6)", "raw_unit": "HV", "normalized_value": null, "role": "indentation_measurement_2_94_n_for_10_s", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20346, "char_end": 20352, "end_exclusive": true, "literal_sha256": "35f461ff6d19ad2dd49d1cd67cab3f922a10dd04e2c7244c5cc631ab7a1e61a5" } } } }, { "sample_id": "800-c", "cells": { "tc_k": { "raw_value": "9.13", "raw_unit": "K", "normalized_value": null, "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19184, "char_end": 19188, "end_exclusive": true, "literal_sha256": "8daf8f8b04da7a6d00ed5852b3790028b14825ebaa2bf2ddf4404c8fabcc4437" } }, "gamma_el": { "raw_value": "5.46", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19257, "char_end": 19261, "end_exclusive": true, "literal_sha256": "f2ae094336db6d7006ef9963a3a57f8a469653fe24d1d174bd233bca880d7027" } }, "beta": { "raw_value": "0.129", "raw_unit": "mJ/mol·K4", "normalized_value": null, "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19330, "char_end": 19335, "end_exclusive": true, "literal_sha256": "13edbf90d092d8a14968788cb27b833f85fb5bc2f18b7739bca2945d18e0390d" } }, "hc1_zero_mt": { "raw_value": "22.2", "raw_unit": "mT", "normalized_value": null, "role": "gl_fit_extrapolation_from_initial_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19403, "char_end": 19407, "end_exclusive": true, "literal_sha256": "32e91c1240d5f0df215a3d318b26dfb6755680982d5f6722a6aed0dae644c0b3" } }, "hc2_m_zero_t": { "raw_value": "13.9", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_magnetization_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19496, "char_end": 19500, "end_exclusive": true, "literal_sha256": "34bb7aff4d9162a3786c527c6494ebf518a7acea7366504be8d41879604f298a" } }, "maki_m": { "raw_value": "1.3", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19593, "char_end": 19596, "end_exclusive": true, "literal_sha256": "9c193c604ad7de942961af97b39ff541f2e611fdf0b93a3044e16dfbd808f41b" } }, "hc2_rho_zero_t": { "raw_value": "15.0", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_resistivity_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19685, "char_end": 19689, "end_exclusive": true, "literal_sha256": "c72ae9676454d7cc0014583a9d0a2e28553d5c62f087c7562b5307ebd1cc84c8" } }, "maki_rho": { "raw_value": "1.3", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_resistivity", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19759, "char_end": 19762, "end_exclusive": true, "literal_sha256": "9c193c604ad7de942961af97b39ff541f2e611fdf0b93a3044e16dfbd808f41b" } }, "xi_m_zero_nm": { "raw_value": "4.9", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19848, "char_end": 19851, "end_exclusive": true, "literal_sha256": "5ecf21708e12d2b3762b9341be022380e87c3a5cd570a424962c37d3391c90dd" } }, "lambda_m_zero_nm": { "raw_value": "161", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19937, "char_end": 19940, "end_exclusive": true, "literal_sha256": "bb668ca95563216088b98a62557fa1e26802563f3919ac78ae30533bb9ed422c" } }, "kappa_m": { "raw_value": "33", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20031, "char_end": 20033, "end_exclusive": true, "literal_sha256": "c6f3ac57944a531490cd39902d0f777715fd005efac9a30622d5f5205e7f6894" } }, "xi_rho_zero_nm": { "raw_value": "4.7", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20119, "char_end": 20122, "end_exclusive": true, "literal_sha256": "db7dc8ce07623b4654a57d0ad29200bdcf4eff470334d40dae8a2675a165372a" } }, "lambda_rho_zero_nm": { "raw_value": "162", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20192, "char_end": 20195, "end_exclusive": true, "literal_sha256": "79d6eaa2676189eb927f2e16a70091474078e2117c3fc607d35cdc6b591ef355" } }, "kappa_rho": { "raw_value": "34", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20286, "char_end": 20288, "end_exclusive": true, "literal_sha256": "86e50149658661312a9e0b35558d84f6c6d3da797f552a9657fe0558ca40cdef" } }, "hardness_hv": { "raw_value": "239(2)", "raw_unit": "HV", "normalized_value": null, "role": "indentation_measurement_2_94_n_for_10_s", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20353, "char_end": 20359, "end_exclusive": true, "literal_sha256": "fd0f45cac425d1caa3af8a61ef641bf4cb9cf521fce45ec93d2ba6670326e142" } } } }, { "sample_id": "1000-c", "cells": { "tc_k": { "raw_value": "9.03", "raw_unit": "K", "normalized_value": null, "role": "tabulated_refined_transition_temperature_criterion_attribution_unresolved", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19193, "char_end": 19197, "end_exclusive": true, "literal_sha256": "d407614cd54fa931f11705a69ffd9d9c44a3d777fce29a43c62880f34fd6fec6" } }, "gamma_el": { "raw_value": "6.62", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "normal_state_specific_heat_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19266, "char_end": 19270, "end_exclusive": true, "literal_sha256": "19511f64684f492d56c677f1f2625c21a413695c9efa2df0054276494b14ee79" } }, "beta": { "raw_value": "0.145", "raw_unit": "mJ/mol·K4", "normalized_value": null, "role": "normal_state_specific_heat_lattice_fit_bcc_and_hcp_contributions", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19338, "char_end": 19343, "end_exclusive": true, "literal_sha256": "a8a9d3a5a4d7f0e21d15a6339499b2d276ba7bcd078dc545bd883fee461573d6" } }, "hc1_zero_mt": { "raw_value": "4.46", "raw_unit": "mT", "normalized_value": null, "role": "gl_fit_extrapolation_from_initial_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19412, "char_end": 19416, "end_exclusive": true, "literal_sha256": "50175d83567cad5f2b16644a37b05c997fc08b840595f71ff3547da24666c8c2" } }, "hc2_m_zero_t": { "raw_value": "14.3", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_magnetization_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19505, "char_end": 19509, "end_exclusive": true, "literal_sha256": "20859fc7798f69d4e4767e2f429bdeac01e15369144dd929b3a51f7663f75187" } }, "maki_m": { "raw_value": "1.3", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_magnetization", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19602, "char_end": 19605, "end_exclusive": true, "literal_sha256": "9c193c604ad7de942961af97b39ff541f2e611fdf0b93a3044e16dfbd808f41b" } }, "hc2_rho_zero_t": { "raw_value": "14.5", "raw_unit": "T", "normalized_value": null, "role": "whh_fit_from_resistivity_transition_onset", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19694, "char_end": 19698, "end_exclusive": true, "literal_sha256": "6978e2340a8503590a60b7d19aae46c4ea02a62986b91628d06ae0e35b011e0d" } }, "maki_rho": { "raw_value": "1.3", "raw_unit": null, "normalized_value": null, "role": "whh_fit_maki_parameter_from_resistivity", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19768, "char_end": 19771, "end_exclusive": true, "literal_sha256": "9c193c604ad7de942961af97b39ff541f2e611fdf0b93a3044e16dfbd808f41b" } }, "xi_m_zero_nm": { "raw_value": "4.8", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19857, "char_end": 19860, "end_exclusive": true, "literal_sha256": "9c7f38a9ac4f5de592be486948ac944aff688f914e3b74e6917c7fe4715a561e" } }, "lambda_m_zero_nm": { "raw_value": "405", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 19945, "char_end": 19948, "end_exclusive": true, "literal_sha256": "a73b320dc0d3a57c03f897eb28ca91e623c5ee635db59476ba3178c90b94019f" } }, "kappa_m": { "raw_value": "84", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_m_and_xi_m", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20040, "char_end": 20042, "end_exclusive": true, "literal_sha256": "44c8031cb036a7350d8b9b8603af662a4b9cdbd2f96e8d5de5af435c9c35da69" } }, "xi_rho_zero_nm": { "raw_value": "4.8", "raw_unit": "nm", "normalized_value": null, "role": "gl_coherence_length_derived_from_hc2_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20128, "char_end": 20131, "end_exclusive": true, "literal_sha256": "9c7f38a9ac4f5de592be486948ac944aff688f914e3b74e6917c7fe4715a561e" } }, "lambda_rho_zero_nm": { "raw_value": "405", "raw_unit": "nm", "normalized_value": null, "role": "gl_penetration_depth_derived_from_hc1_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20200, "char_end": 20203, "end_exclusive": true, "literal_sha256": "a73b320dc0d3a57c03f897eb28ca91e623c5ee635db59476ba3178c90b94019f" } }, "kappa_rho": { "raw_value": "84", "raw_unit": null, "normalized_value": null, "role": "gl_ratio_derived_from_lambda_rho_and_xi_rho", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20295, "char_end": 20297, "end_exclusive": true, "literal_sha256": "44c8031cb036a7350d8b9b8603af662a4b9cdbd2f96e8d5de5af435c9c35da69" } }, "hardness_hv": { "raw_value": "230(2)", "raw_unit": "HV", "normalized_value": null, "role": "indentation_measurement_2_94_n_for_10_s", "status": "reported", "source_locator_id": "2024-table-2", "literal": { "char_start": 20360, "char_end": 20366, "end_exclusive": true, "literal_sha256": "94ede2f93f32a924602aae1efa6be67db1af1dd7e4fba50d05ef165152fd75ca" } } } } ], "tc_criterion_attribution": "refined_hc2_analysis_context_without_calorimetric_midpoint_assignment", "specific_heat_phase_scope": "Both bcc and hcp contribute to the normal-state γel and β fits.", "source_zero_temperature_values": "Source model fits or derived estimates; no new calculation." }, "gap_fits": { "source_id": "2024", "label": "2024 electronic specific-heat fits", "columns": [ { "field": "gap_zero_mev", "label": "Δ(0)", "raw_unit": "meV" }, { "field": "gamma_residual", "label": "Residual γel′", "raw_unit": "mJ/mol·K2" }, { "field": "gap_ratio", "label": "2Δ(0)/(kB Tc)", "raw_unit": null }, { "field": "normalized_jump", "label": "ΔCel/[(γel−γel′)Tc]", "raw_unit": null } ], "rows": [ { "sample_id": "400-c", "cells": { "gap_zero_mev": { "raw_value": "1.16", "raw_unit": "meV", "normalized_value": null, "role": "electronic_specific_heat_exponential_gap_fit", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36000, "char_end": 36004, "end_exclusive": true, "literal_sha256": "16ffcff2eb9b46c0e9f4eca8c9725dd5bc64f18b39cc98a56dc7f35c5174954d" } }, "gamma_residual": { "raw_value": "2.8", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "residual_specific_heat_fit_source_attributed_to_hcp_phase", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36006, "char_end": 36009, "end_exclusive": true, "literal_sha256": "c020bad937ece011339d7447ee0ac9fa11686eea100845466c64863f161899f1" } }, "gap_ratio": { "raw_value": "3.22", "raw_unit": null, "normalized_value": null, "role": "source_calculated_2_delta_zero_over_kb_tc_ratio", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36517, "char_end": 36521, "end_exclusive": true, "literal_sha256": "70159003c3341c3776f60c4b5a50ba2e3b26295aa0f27a26ba248cb6fc7ef60d" } }, "normalized_jump": { "raw_value": "1.63", "raw_unit": null, "normalized_value": null, "role": "source_estimated_normalized_specific_heat_jump_midpoint_tc", "status": "reported", "source_locator_id": "2024-gap-jump", "literal": { "char_start": 37894, "char_end": 37898, "end_exclusive": true, "literal_sha256": "48c1f254d3399d2270446c1806a143e360020c32cde30f1ba92427eb615cafaf" } } } }, { "sample_id": "600-c", "cells": { "gap_zero_mev": { "raw_value": "1.73", "raw_unit": "meV", "normalized_value": null, "role": "electronic_specific_heat_exponential_gap_fit", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36045, "char_end": 36049, "end_exclusive": true, "literal_sha256": "00b0b4a5c2373d299e6248e6959f6af491eed4fca879657bfd9b7d7a52325e49" } }, "gamma_residual": { "raw_value": "2.7", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "residual_specific_heat_fit_source_attributed_to_hcp_phase", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36071, "char_end": 36074, "end_exclusive": true, "literal_sha256": "0faf54c7569cac28ec5462f872384f7c0de0d9d7c6290d53579c916e32f8e3d1" } }, "gap_ratio": { "raw_value": "4.43", "raw_unit": null, "normalized_value": null, "role": "source_calculated_2_delta_zero_over_kb_tc_ratio", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36523, "char_end": 36527, "end_exclusive": true, "literal_sha256": "d808f69684a949a2a4bc19c86c47c0261fedfd022737e11118bdf7409a0153c5" } }, "normalized_jump": { "raw_value": "2.83", "raw_unit": null, "normalized_value": null, "role": "source_estimated_normalized_specific_heat_jump_midpoint_tc", "status": "reported", "source_locator_id": "2024-gap-jump", "literal": { "char_start": 37900, "char_end": 37904, "end_exclusive": true, "literal_sha256": "164cb941812dafd93e36fae1c9dc44b1fac6c5874a739c4db8911230783338a6" } } } }, { "sample_id": "800-c", "cells": { "gap_zero_mev": { "raw_value": "1.84", "raw_unit": "meV", "normalized_value": null, "role": "electronic_specific_heat_exponential_gap_fit", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36110, "char_end": 36114, "end_exclusive": true, "literal_sha256": "92652390b02202b690c0b54355ceacff5475a507ed0145e21ba65b03a382ae91" } }, "gamma_residual": { "raw_value": "2.8", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "residual_specific_heat_fit_source_attributed_to_hcp_phase", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36116, "char_end": 36119, "end_exclusive": true, "literal_sha256": "c020bad937ece011339d7447ee0ac9fa11686eea100845466c64863f161899f1" } }, "gap_ratio": { "raw_value": "4.85", "raw_unit": null, "normalized_value": null, "role": "source_calculated_2_delta_zero_over_kb_tc_ratio", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36529, "char_end": 36533, "end_exclusive": true, "literal_sha256": "163fbb83a83d63055d19c596aa3c5f3abb65cc8b1516662297618b3e5c67c739" } }, "normalized_jump": { "raw_value": "3.97", "raw_unit": null, "normalized_value": null, "role": "source_estimated_normalized_specific_heat_jump_midpoint_tc", "status": "reported", "source_locator_id": "2024-gap-jump", "literal": { "char_start": 37983, "char_end": 37987, "end_exclusive": true, "literal_sha256": "0a61e757f6221e96f981e29c9b3336ba869a7ef1e97d3ab9231e7daba3b84073" } } } }, { "sample_id": "1000-c", "cells": { "gap_zero_mev": { "raw_value": "1.66", "raw_unit": "meV", "normalized_value": null, "role": "electronic_specific_heat_exponential_gap_fit", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36159, "char_end": 36163, "end_exclusive": true, "literal_sha256": "363a35aa53455c97d77bcfeeff69c80d55c72f7ebf20dea44ea56d85ffbec7dc" } }, "gamma_residual": { "raw_value": "2.6", "raw_unit": "mJ/mol·K2", "normalized_value": null, "role": "residual_specific_heat_fit_source_attributed_to_hcp_phase", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36165, "char_end": 36168, "end_exclusive": true, "literal_sha256": "af3266e6d0f3bba206c2e954c21ff72182e440557702a3f79f4c6bdfb577fed5" } }, "gap_ratio": { "raw_value": "4.56", "raw_unit": null, "normalized_value": null, "role": "source_calculated_2_delta_zero_over_kb_tc_ratio", "status": "reported", "source_locator_id": "2024-calorimetry", "literal": { "char_start": 36539, "char_end": 36543, "end_exclusive": true, "literal_sha256": "8b08f387373618195545c4d4fd2e259ed42f79f294133af002f5c2d0d09103a5" } }, "normalized_jump": { "raw_value": "2.68", "raw_unit": null, "normalized_value": null, "role": "source_estimated_normalized_specific_heat_jump_midpoint_tc", "status": "reported", "source_locator_id": "2024-gap-jump", "literal": { "char_start": 37993, "char_end": 37997, "end_exclusive": true, "literal_sha256": "9964c8ae509e89f6db0c25641d8dbc8e108dca8706b3a8506665b5b1304cfaf7" } } } } ], "as_cast_status": "not_established_in_source_analysis", "as_cast_reason": "The paper excludes the as-cast sample from these superconducting specific-heat fits; transition broadening prevents evaluating its gap ratio.", "interpretation_scope": "Source fit and model-ratio estimates. Author discussion of possible strong coupling does not establish a global pairing classification or electron–phonon λ." }, "tc_2023": { "source_id": "2023", "source_locator_id": "2023-table-1", "label": "2023 Table 1: original reported transition temperatures", "columns": [ { "field": "tc_k", "label": "Tc", "raw_unit": "K" } ], "rows": [ { "sample_id": "as-cast", "cells": { "tc_k": { "raw_value": "7.9", "raw_unit": "K", "normalized_value": null, "role": "source_table_transition_temperature", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13444, "char_end": 13447, "end_exclusive": true, "literal_sha256": "1e81bf048f2b3ca9f5765fe41db004e94c25c22dfcd58a798d29f97833296d81" } } } }, { "sample_id": "400-c", "cells": { "tc_k": { "raw_value": "8.4", "raw_unit": "K", "normalized_value": null, "role": "source_table_transition_temperature", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13642, "char_end": 13645, "end_exclusive": true, "literal_sha256": "163c820d957641208e645d35d74837183b2638bba77e6e069f2fed1c41312dd7" } } } }, { "sample_id": "800-c", "cells": { "tc_k": { "raw_value": "9.0", "raw_unit": "K", "normalized_value": null, "role": "source_table_transition_temperature", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 13840, "char_end": 13843, "end_exclusive": true, "literal_sha256": "b7edbb1d306a68faf170673ebef76f1dfef2045c0c190bdc1bb37837e37504a4" } } } }, { "sample_id": "1000-c", "cells": { "tc_k": { "raw_value": "8.7", "raw_unit": "K", "normalized_value": null, "role": "source_table_transition_temperature", "status": "reported", "source_locator_id": "2023-table-1", "literal": { "char_start": 14038, "char_end": 14041, "end_exclusive": true, "literal_sha256": "8719c8b9d63c644df3a5b778698dbdaa3c3f1b746f3cbb41b28a5f79a8989229" } } } } ], "criterion_context_id": "2023-tc-definition", "cross_publication_relation": "Distinct source reports; no automatic reconciliation with 2024 Table 2 values." }, "limitations": [ "Source sample labels describe preparation groups, not typed catalogue sample or state IDs.", "Annealing temperature and four-day hold are processing conditions, not superconducting measurement conditions. As-cast is not represented as a 0 °C anneal.", "A formula match, a shared author group or a citation does not establish the same physical specimen across the papers.", "Original PDF and full derived text remain private; metadata publishes source values, paraphrased context and hash-only locations.", "No pressure value is supplied from missing source fields, and zero-temperature fitted values do not establish measurements at 0 K.", "No scientific acceptance, human gold benchmark, canonical promotion, new DFT or ML permission is created." ], "counts": { "sources": 2, "source_sample_labels": 5, "phase_rows_2024": 10, "phase_rows_2023": 8, "parameter_fields": 15, "parameter_cells": 75, "tc_cells_2023": 4, "gap_fit_samples_2024": 4, "gap_fit_cells_2024": 16, "reported_value_cells": 210, "source_blank_cells": 9, "independent_experiment_count_established": false } }