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Superconductivity in PtPb4 with possible nontrivial band topology

C. Q. Xu, B. Li, L. Zhang, J. Pollanen, X. L. Yi, X. Z. Xing, Y. Liu, J. H. Wang, Zengwei Zhu, Z. X. Shi, Xiaofeng Xu, X. Ke

DOI 10.1103/PhysRevB.104.125127 · Physical Review B

T1

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Abstract

Superconductivity in topological quantum materials is much sought after, as it represents the key avenue to searching for topological superconductors, which host a full pairing gap in the bulk but Majorana bound states at the surface. To date, however, the simultaneous realization of nontrivial band topology and superconductivity in the same material under ambient conditions remains rare. In this paper, we study both superconducting and topological properties of the binary compound PtPb4 (Tc∼2.7 K) that was recently reported to exhibit large Rashba splitting, inherent to the heavy 5d Pt and 6p Pb. We show that in PtPb4, the specific heat jump at Tc reaches ΔC/γTc∼1.70±0.04, larger than the 1.43 expected for weak-coupling BCS superconductors. Moreover, the measurement of quantum oscillation suggests the possibility of a topological band structure, which is further studied by density functional theory calculations. Our study may stimulate future experimental and theoretical investigations in this intriguing material.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
PtPb4

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

2.7Pressure unresolvedonset
PtPb4

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

2.7Pressure unresolvedonset
PtPb4

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

2.7Pressure unresolvedonset

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