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Discrete superconducting phases in proton-intercalated FeSe thin flakes

W. X. Wang, B. Lei, C. S. Zhu, J. H. Cui, W. Z. Zhuo, Z. J. Xiang, X. G. Luo, X. H. Chen

DOI 10.1103/PhysRevB.106.014509 · Physical Review B

T1

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Abstract

We have successfully manipulated the electronic properties of FeSe thin flakes based on a field-effect transistor with a solid proton conductor as the gate dielectric. The phase diagram as a function of gate voltage demonstrates three evident discrete superconducting phases with Tc corresponding to ∼8, ∼34, and ∼42 K, respectively, which is similar to those observed in LixFeSe and NaxFeSe by tuning Li or Na content with the solid-ion-conductor gating technique. In the protonation process, the final state with a saturation of the amount of hydrogen ions is reached at a moderately low gate voltage. It suggests that such a device based on a proton conductor can be used to modulate the physical properties by controlling the intercalated proton content and to explore the hydrogen storage capacity of materials.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
FeSe

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7.3Pressure not reportedonset
FeSe

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34Pressure not reportedonset
FeSe

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42Pressure not reportedonset
FeSe

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41Pressure not reportedmidpoint
FeSe

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39Pressure not reportedzero_resistance
FeSe

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8Pressure not reportedunknown
FeSe

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36.7Pressure not reportedunknown
FeSe

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65Pressure not reportedunknown
(Li0.8Fe0.2)OHFeSe

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43Pressure not reportedunknown
FeSe

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41Pressure not reportedunknown

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