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Superconducting ground state study of the valence-skipped compound AgSnSe2

A. Kataria, Arushi, S. Sharma, T. Agarwal, M. Pula, J. Beare, S. Yoon, Y. Cai, K. M. Kojima, G. M. Luke, R. P. Singh

DOI 10.1103/PhysRevB.107.174517 · Physical Review B

T1

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Abstract

Valence-skipped superconductors are natural candidates for unconventional superconductivity because they can exhibit a negative effective, attractive interaction for electron pairing. This work reports comprehensive x-ray diffraction, magnetization, specific heat, and muon spin rotation and relaxation measurements (μSR) on the valence-skipped compound AgSnSe2. The temperature dependences of the electronic specific heat [Cel(T)] and the upper critical field [Hc2(T)] provide evidence of two-gap superconductivity, which is also confirmed by our transverse-field μSR measurements. Zero-field μSR measurements reveal at most a slight increase [∼0.002(1)μs−1] in relaxation in the superconducting state, much less than reported in a range of superconductors with broken time-reversal symmetry. Further measurements with greatly improved statistics will be required to make a definitive determination of the possible presence of broken time-reversal symmetry.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
AgSnSe2

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

4.91Pressure not reportedunknown
AgSnSe2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

4.74Pressure not reportedmidpoint
AgSnSe2

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

4.91Pressure not reportedunknown

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