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Higher-order topological and nodal superconducting transition-metal sulfides MS (M=Nb and Ta)

Yipeng An, Juncai Chen, Yong Yan, Jinfeng Wang, Yinong Zhou, Zhengxuan Wang, Chunlan Ma, Tianxing Wang, Ruqian Wu, Wuming Liu

DOI 10.1103/PhysRevB.108.054519 · Physical Review B

T1

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Abstract

Intrinsic topological superconducting materials are exotic and vital to develop the next-generation topological superconducting devices, topological quantum calculations, and quantum information technologies. Here, we predict the topological and nodal superconductivity of NiAs-type MS (M=NbandTa) transition-metal sulfides. We reveal their higher-order topology nature with an index of Z4=2. These materials have a higher Tc than the Nb or Ta metal superconductors due to their flat band and strong electron-phonon coupling nature. Electron doping and lighter isotopes can effectively enhance the Tc. Our findings show that the MS (M=NbandTa) systems can be platforms to study exotic physics in the higher-order topological superconductors, and provide a theoretical support to utilize them as the topological superconducting devices in the field of advanced topological quantum calculations and information technologies.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
NbS

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

16.27Pressure not reportedunknown
TaS

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12.3Pressure not reportedunknown
Nb

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

9.2Pressure not reportedunknown

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