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Room-temperature structure of the 90-K bulk superconductor YBa2Cu3O8−x

Y. LePage, W. R. McKinnon, J. M. Tarascon, L. H. Greene, G. W. Hull, and D. M. Hwang

DOI 10.1103/PhysRevB.35.7245 · Physical Review B

T1

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Abstract

The 90-K superconducting phase of Y-Ba-Cu-O has been isolated, and its structure at room temperature determined by single-crystal x-ray diffraction. The material is an oxygen-defect perovskite, with composition YBa2Cu3O8−x. Entire planes of oxygen atoms between copper atoms are missing from the perovskite structure. The result is a quasi-two-dimensional structure in which sandwiches of Ba2Cu3O8−y are separated by layers of Y.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O8-x

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90Pressure unresolvedonset
Y1.05Ba1.95Cu3Oy

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90Pressure unresolvedonset
Y1.05Ba1.95Cu3Oy

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92Pressure unresolvedonset
Y1.05Ba1.95Cu3Oy

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85Pressure unresolvedmidpoint
Y1.05Ba1.95Cu3Oy

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78Pressure unresolvedzero_resistance
YBa2Cu3O9-x

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90Pressure not reportedunknown

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