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Vibrational spectra and lattice instabilities in the high-Tc superconductors YBa2Cu3O7 and GdBa2Cu3O7

I. Božović, D. Mitzi, M. Beasley, A. Kapitulnik, T. Geballe, S. Perkowitz, G. L. Carr, B. Lou, R. Sudharsanan, S. S. Yom

DOI 10.1103/PhysRevB.36.4000 · Physical Review B

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Abstract

The exceptionally high Tc of layered cuprates was proposed recently as originating from electronically driven structural instabilities. We have studied the infrared and Raman spectra of YBa2Cu3O7−δ and GdBa2Cu3O7−δ over a broad range of temperatures, from 10 to 300 K. We observed neither mode softening nor any other spectroscopic signature of lattice instabilities.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O7-δ

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97Pressure not reportedonset
GdBa2Cu3O7-δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

92Pressure not reportedonset
La1.85Sr0.15CuO4-y

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
EuBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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