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Superconductivity and crystal structure in the La-Ba-Cu-O system

C. Dong, J. K. Liang, G. C. Che, S. S. Xie, Z. X. Zhao, Q. S. Yang, Y. M. Ni, G. R. Liu

DOI 10.1103/PhysRevB.37.5182 · Physical Review B

T1

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Abstract

A series of samples with nominal compositions La1−xBaxCu1O3−y was prepared by solid-state reaction. The subsolidus phase relation in the CuO-rich region of the La-Ba-Cu-O system has been determined by an x-ray diffraction method. Two ternary compounds were confirmed to exist in the system. The tetragonal or pseudotetragonal phase (Ba2−zLaz)La1Cu3O7+δ has a wide homogenous phase range from z=0.095 to z=0.578, and a crystal structure closely related to the structure of Ba2YCu3O7−δ. Superconductivity of compounds in this system was studied by resistivity and ac susceptibility measurements. The relation between crystal structure and the superconductivity is discussed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La4Ba1Cu5O13.4

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—Pressure not reportedunknown
La4Ba1Cu5O13.4

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—Pressure not reportedunknown
La2Ba3Cu5O5.5-p

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—Pressure not reportedunknown
Y2Ba3Cu5O1-y

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89Pressure not reportedzero_resistance
Ba2YCu3O7-δ

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90Pressure not reportedunknown

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