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Structure and physical properties of single crystals of the 84-K superconductor Bi2.2Sr2Ca0.8Cu2O8+δ

S. A. Sunshine, T. Siegrist, L. F. Schneemeyer, D. W. Murphy, R. J. Cava, B. Batlogg, R. B. van Dover, R. M. Fleming, S. H. Glarum, S. Nakahara, R. Farrow, J. J. Krajewski, S. M. Zahurak, J. V. Waszczak, J. H. Marshall, P. Marsh, L. W. Rupp, Jr., W. F. Peck

DOI 10.1103/PhysRevB.38.893 · Physical Review B

T1

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Abstract

Single crystal sof the 84-K superconductor Bi2.2Sr2Ca0.8Cu2O8+δ were characterized by x-ray diffraction, dc magnetic susceptibility, electrical resistivity, and microwave absorption. The structure has [CuO2]∞ planes separated by calcium atoms, edge-shared bismuth oxide double layers, and an incommensurate superlattice along b with a period of 4.76. The in-plane resistivity above Tc is linear in T, with ρRT=130 μΩ cm. Initial results on Pb substitution yielding Tc's of 107 K are reported.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Bi2.2Sr2Ca0.8Cu2O8+δ

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84Pressure not reportedonset
Bi2.2Sr2Ca0.8Cu2O8+δ

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

84Pressure not reportedonset

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