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Superconducting (1:1:2:2)-type layered cuprates of the formula TlCA1−xLxSr2Cu2Oy (L=Y or rare-earth element)

C. N. R. Rao, A. K. Ganguli, R. Vijayaraghavan

DOI 10.1103/PhysRevB.40.2565 · Physical Review B

T1

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Abstract

The TlCa1−xLxSr2Cu2Oy (L=Y or a rare earth element) series of cuprates possessing a (1:1:2:2)-type layered structure exhibit superconductivity in the 60–90-K region. The TlCa1−xLxSr2Cu2Oy (x=1) series of cuprates also possess the (1:1:2:2)-type structure, but are not superconducting. A change in the conduction mechanism seems to occur in the TlCa1−xLxSr2Cu2Oy system with a change in x. Partial substitution of Tl by Pb does not favor superconductivity in this series of cuprates.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
TlCa1-xLxSr2Cu2Oy

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75Pressure not reportedonset
TlCa0.5La0.5Sr2Cu2Oy

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75Pressure not reportedonset
TlCa0.5Nd0.5Sr2Cu2Oy

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75Pressure not reportedonset
TlCa0.5Y0.5Sr2Cu2Oy

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75Pressure not reportedonset
TlCa0.5Pr0.5Sr2Cu2Oy

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75Pressure not reportedonset
TlCaSr2Cu2O7

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50Pressure not reportedunknown
Tl0.5Pb0.5CaSr2Cu2Oy

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90Pressure not reportedunknown
Tl0.5Pb0.5Ca2Sr2Cu3Oy

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120Pressure not reportedunknown

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