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Magnetic ordering and superconductivity in Y1−xPrxBa2Cu3O7−y

A. Kebede, C. S. Jee, J. Schwegler, J. E. Crow, T. Mihalisin, G. H. Myer, R. E. Salomon, P. Schlottmann, M. V. Kuric, S. H. Bloom, R. P. Guertin

DOI 10.1103/PhysRevB.40.4453 · Physical Review B

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Abstract

An extensive study of magnetic, thermal, transport, and structural properties of the alloy Y1−xPrxBa2Cu3O7−y is presented. The endpoints of the alloy series are a high-temperature superconductor Y-Ba-Cu-O and an antiferromagnetic semiconductor (Pr-Ba-Cu-O, TN=17 K). The superconducting transition temperature is reduced with increasing Pr concentration following the Abrikosov-Gorkov pair-breaking curve with critical concentration xcr=0.62. Alloying also reduces the Néel temperature approximately linearly with the Y content, and there is a concentration region (0.4<x<0.6) where antiferromagnetism and superconductivity is suggested to coexist. The specific heat, the susceptibility, the magnetic ordering, and the metal-to-semiconductor transition seen in the resistivity are consistent with the picture that Y3+ is replaced by Pr4+ with some degree of valence admixture of the Pr3+ configuration.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O7-y

Archive — visibility unverified

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92Pressure not reportedunknown
YBa2Cu3O7-y

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

90Pressure not reportedunknown
(Y1-xPrx)Ba2Cu3O7-y

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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