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Superconducting energy gap and a normal-state excitation in Ba0.6K0.4BiO3

Z. Schlesinger, R. T. Collins, J. A. Calise, D. G. Hinks, A. W. Mitchell, Y. Zheng, B. Dabrowski, N. E. Bickers, D. J. Scalapino

DOI 10.1103/PhysRevB.40.6862 · Physical Review B

T1

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Abstract

We report the first measurement of the energy gap of the high-temperature bismuth oxide superconductor Ba0.6K0.4BiO3 (Tc≃30 K). With temperature- and magnetic-field-dependent infrared reflectivity measurements, we obtain a reduced energy gap of 2Δ/kTc≃3.5±0.5, consistent with a BCS-type mechanism with moderate or weak coupling. In the normal state a broad peak in the infrared conductivity is observed near 5000 cm−1. This unusual infrared behavior is common to both the BaPb1−xBixO3 and the Ba1−xKxBiO3 systems and may provide a fundamental clue to the mechanism of superconductivity in the cubic bismuth oxides.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Ba0.6K0.4BiO3

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30Pressure not reportedunknown
Ba0.6K0.4BiO3

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29Pressure not reportedonset
Ba0.6K0.4BiO3

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26Pressure not reportedonset
Ba1-xKxBiO3

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30Pressure not reportedunknown
BaPb1-xBixO3

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12Pressure not reportedunknown

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