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Glass behavior and the H-T phase diagram of the high-Tc ceramic superconductors YBa2Cu3O7, EuBa2Cu3O7, and GdBa2Cu3O7

J. Schaf, P. Pureur, J. V. Kunzler

DOI 10.1103/PhysRevB.40.6948 · Physical Review B

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Abstract

We report systematic field-cooled (FC) and zero-field-cooled (ZFC) diamagnetic susceptibility measurements in polycrystalline samples of the high-Tc oxide superconductors RBa2Cu3O7, where R=Y, Eu, or Gd. We focus mainly on the temperature range near Tc, where the FC and ZFC curves split up below a characteristic temperature, similar to the behavior of spin glasses. This temperature depends on the applied magnetic field and defines a crossover line in the H-T plane separating ergodic and nonergodic behavior, in close resemblance to what is found in conventional spin glasses. We suggest that this is a general characteristic of the ceramic oxide superconductors. Moreover, our data allow us to obtain a more detailed high-temperature H-T phase diagram, where a lower temperature bound for the superconducting glasslike state is proposed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O7

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—Pressure not reportedonset
EuBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedonset
GdBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedonset

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