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Metallization and superconducting properties of YBa2Cu3O6.2Bry

H. B. Radousky, R. S. Glass, P. A. Hahn, M. J. Fluss, R. G. Meisenheimer, B. P. Bonner, C. I. Mertzbacher, E. M. Larson, K. D. McKeegan, J. C. O’Brien, J. L. Peng, R. N. Shelton, K. F. McCarty

DOI 10.1103/PhysRevB.41.11140 · Physical Review B

T1

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Abstract

Low-temperature (260 °C) and short-time (>5-min) treatment of initially insulating YBa2Cu3O6.2 with Br2 gas converts the material into a 90-K superconductor. Bromine diffusion is found to be four orders of magnitude greater than oxygen diffusion at the same temperature. The crystal structure, phase purity, microstructure, thermal stability, and oxygen content have been studied using x-ray-diffraction Rietveld analysis, Raman spectroscopy, x-ray-fluorescence microprobe, and thermal gravimetric analysis. Superconducting and normal-state properties of the brominated material have been studied with diffuse infrared reflectivity and magnetization.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O6.2Bry

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

92Pressure not reportedonset
YBa2Cu3O6.94

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

92Pressure not reportedunknown
YBa2Cu3O6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

90Pressure not reportedunknown

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