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Long-range Coulomb interactions and the onset of superconductivity in the high-Tc materials

S. Doniach, M. Inui

DOI 10.1103/PhysRevB.41.6668 · Physical Review B

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Abstract

The Ginzburg-Landau functional for a superconductor is extended to include a quantum-fluctuation term arising from imperfect screening of the long-range Coulomb interaction. At low temperatures the resulting quantum x-y model shows a second-order phase transition between a superconducting state and an insulating state as a function of the ratio of the phase stiffness to the Coulomb energy measured on the scale of the mean pair spacing. By relating the functional formulation to a BCS-type model of high-temperature superconductivity in the strongly correlated regime, we show that the phase stiffness is proportional to doping away from the 1/2-full Mott insulating state. We discuss application of the model as a mechanism for the onset of superconductivity of the CuO2-based high-Tc materials above a critical doping level. Transport and optical properties of materials with reduced transition temperature are calculated.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La2-xSrxCuO4

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—Pressure not reportedunknown
YBa2Cu3O7-y

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Nd2-xCexCuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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