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Effects of Zn substitution for Cu on superconducting and normal-state properties of (La,Sr)2CuO4, (Nd,Ce,Sr)2CuO4, and (Nd,Ce)2CuO4

S. Ikegawa, T. Yamashita, T. Sakurai, R. Itti, H. Yamauchi, S. Tanaka

DOI 10.1103/PhysRevB.43.2885 · Physical Review B

T1

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Abstract

Superconducting and normal-state properties of Zn-doped samples of La1.85Sr0.15Cu1−xZnxO4−δ (T phase), Nd1.4Ce0.2Sr0.4Cu1−xZnxO4−δ (T* phase), and Nd1.85Ce0.15Cu1−xZnxO4−δ (T’ phase) are investigated for Zn content x in the range of 0–0.04. Zn doping alters the lattice parameters for the T and T* phases but does not for the T’ phase. For all of the T, T*, and T’ phases, Tc, the Meissner signal, and the shielding signal monotonically decrease for increasing x. From the magnetic-susceptibility measurement, it is suspected that isolated Cu spins are induced around doped Zn in the T phase. As the Zn content increases, the magnitude of the Hall coefficient decreases in both T and T’ phases, while the carrier density, estimated from a chemical analysis, remains constant. Possible mechanisms for this are discussed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La1.85Sr0.15Cu1-xZnxO4-δ

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—Pressure not reportedunknown
La1.85Sr0.15Cu1-xZnxO4-δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Nd1.4Ce0.2Sr0.4Cu1-xZnxO4-δ

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—Pressure not reportedunknown
Nd1.4Ce0.2Sr0.4Cu1-xZnxO4-δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Nd1.85Ce0.15Cu1-xZnxO4-δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Nd1.85Ce0.15Cu1-xZnxO4-δ

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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