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Magnetization of superconducting Hg3NbF6 and Hg3TaF6

Thomas W. Krause, T. Olech, P. K. Ummat, W. R. Datars

DOI 10.1103/PhysRevB.47.11275 · Physical Review B

T1

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Abstract

The magnetization of the bulk superconducting transitions of Hg3NbF6 and Hg3TaF6 was measured in the temperature range from 0.1 to 1 K and in magnetic fields from 0 to 50 G. Measurements were performed on both samples in the zero-field-cooled (ZFC) and field-cooled (FC) modes. The magnetization was also measured as the sample warmed through its superconducting transition in the same field in which it had been cooled; this was referred to as the return-warming (RW) mode. A large difference in magnitude between the ZFC and FC modes for both samples indicated the presence of multiply connected regions (or type-II superconductivity). Evidence for both samples of the trapping of flux due to inhomogeneities and defects was provided by the hysteresis measured between the FC and RW modes. The observation of excess magnetization above the critical temperature in magnetic fields below 30 G was attributed to a proximity effect between the observed free mercury and the Hg3NbF6 and Hg3TaF6 metals. For the average of the data from the three modes, the Hg3NbF6 sample exhibited a critical field at absolute zero, Hc(0), of 150 G and a critical temperature, Tc, of 0.38 K. The Hg3TaF6 had a lower Hc(0) of 60 G, with a Tc of 0.44 K.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Hg3NbF6

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0.38Pressure unresolvedmidpoint
Hg3TaF6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

0.44Pressure unresolvedmidpoint
Hg3-δAsF6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

0.42Pressure not reportedunknown
Hg3-δSbF6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

0.42Pressure not reportedunknown

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