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Electronic structure and superconducting energy gap in Rb3C60 single crystals studied by photoemission spectroscopy

Chun Gu, B. W. Veal, R. Liu, A. P. Paulikas, P. Kostic, H. Ding, K. Gofron, J. C. Campuzano, J. A. Schlueter, H. H. Wang, U. Geiser, J. M. Williams

DOI 10.1103/PhysRevB.50.16566 · Physical Review B

T1

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Abstract

We report an ultrahigh-resolution photoemission study of Rb3C60 single crystals (Tc=30.5 K) and the measurement of the superconducting energy gap. The crystals were cleaved at 13 K to expose the (111) plane. They show a sharp Fermi cutoff above Tc and a superconducting gap opening below Tc (2Δ/kBTc∼4.1 at 13 K). The valence band shows a ∼0.15-eV-wide band near EF that is consistent with calculations, and a broad band at 0.15–1.3 eV, possibly contributed by the surface C60 layer.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Rb3C60

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30.5Pressure not reportedonset
Rb3C60

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

30.5Pressure not reportedonset
K3C60

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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