← Back to search

NMR studies of superconducting Na2AC60 (A=Cs, Rb, and K) fullerides

Y. Maniwa, T. Saito, K. Kume, K. Kikuchi, I. Ikemoto, S. Suzuki, Y. Achiba, I. Hirosawa, M. Kosaka, K. Tanigaki

DOI 10.1103/PhysRevB.52.R7054 · Physical Review B

T1

Active bibliographic source — not scientific approval

Bibliographic access preserves source history; it does not approve extracted materials or validate reported claims. Review warnings on each occurrence separately.

Abstract

Multiple-nuclei NMR investigations on fullerides that contain sodium, Na2AC60 (A=K,Rb,Cs), with a simple-cubic structure are reported. The density of states at the Fermi level vs lattice constant correlation was determined. The superconductivity in Na2AC60 connot be described by the same parameters as those of the other A3C60 superconductors within the Bardeen-Cooper-Schrieffer theory. We find that structural imperfection plays an important role in determining the electronic states and onset of superconductivity in Na2AC60. Evidence for the orientational ordering transition was also found with Na23 NMR for A=Cs, Rb, and K.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Na2CsC60

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Na2RbC60

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Na2KC60

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
KC60

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

18Pressure not reportedonset

Similar papers