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BCS theory of superconductivity in a pseudofullerene system: The case of the isohexaiminocryptand molecular solid

A. Devos, M. Lannoo

DOI 10.1103/PhysRevB.56.14703 · Physical Review B

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Abstract

We examine the theoretical possibility of superconductivity in molecular crystals of the isohexaiminocryptand (IHIC), a molecule which has some properties in common with C60. Using the standard BCS theory with electron-phonon coupling we compare the predictions for the critical temperature Tc in the two cases. Our calculation shows that IHIC is likely to give rise to a larger value of Tc. The origin of this difference is discussed together with possible extensions. A comparison is made with some recent experimental data which show some evidence for a Tc of order 50 K in this material.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
IHIC

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50Pressure not reportedunknown

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