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Two types of magnetism in the magnetic superconductor TmNi2B2C related to the degree of carbon-site occupancy

A. M. Mulders, P. C. M. Gubbens, U. Gasser, C. Baines, K. H. J. Buschow

DOI 10.1103/PhysRevB.57.10320 · Physical Review B

T1

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Abstract

A combined 169Tm Mössbauer spectroscopy and μ+SR (muon spin rotation) study is presented on a polycrystalline sample of TmNi2B2C. The first experimental technique shows the coexistence of two types of Tm 4f magnetism at 0.3 K, one related to a magnetic Tm moment of 4.3(1)μB and the other to a small Tm moment of ∼0.1μB. This second type of magnetism is suggested to be caused by carbon vacancies present in TmNi2B2C. These C vacancies locally modify the crystalline electric field and therefore the Tm 4f magnetism. Since these vacancies are ideal cavities in which muons can reside, it is suggested that μ+SR only probes this ∼0.1μB magnetism.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
TmNi2B2C

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10.3Pressure not reportedunknown
TmNi2B2C

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

10.8Pressure not reportedunknown
DyNi2B2C

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

6Pressure not reportedunknown

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