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Scaling of magnetization and some basic parameters of Ba1−xKxBiO3+y superconductors near Tc

S. N. Barilo, S. V. Shiryaev, V. I. Gatalskaya, J. W. Lynn, M. Baran, H. Szymczak, R. Szymczak, D. Dew-Hughes

DOI 10.1103/PhysRevB.58.12355 · Physical Review B

T1

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Abstract

Reversible magnetization and hysteresis loops have been studied over wide ranges of magnetic field and temperature for single crystals of Ba1−xKxBiO3+y(x=0.34, 0.37, 0.41, and 0.46). The main goals were to derive critical parameters of superconductors with a cubic structure as well as to explain the origin of flux pinning and peak (fishtail) effect observed in all samples. Values of the electron-phonon interaction constant of λph∼1, ∼0.76, and 0.9 for Ba1−xKxBiO3+y with x=0.34, x=0.37, and x=0.41, respectively, have been obtained. The data show that this family belongs to oxide superconductors with at least an intermediate strength of coupling. The pinning force density has been scaled into a single curve for wide field and temperature ranges. The functional form of the scaling curve reflects various mechanisms of flux pinning. For Ba0.54K0.46BiO3+y the peak effect is mainly due to a dynamical contribution. However, the fishtail for Ba1−xKxBiO3+y with x=0.34, 0.37, and 0.41 has its origin in the crossover between two pinning mechanisms induced by external magnetic field and/or temperature. For the Ba0.59K0.41BiO3+y crystal a seeded growth-induced anisotropy was found to be responsible for differences in low-field susceptibility and in hysteresis loops observed for different magnetic-field orientations.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Ba1-xKxBiO3+y

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—Pressure not reportedunknown
Ba0.54K0.46BiO3+y

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—Pressure not reportedunknown
Ba0.59K0.41BiO3+y

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—Pressure not reportedunknown
Ba1-xKxBiO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

30Pressure not reportedunknown
Ba0.62K0.38BiO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Ba0.7K0.3BiO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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