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Electronic structure of the superconducting layered perovskite niobate

Izumi Hase, Yoshikazu Nishihara

DOI 10.1103/PhysRevB.58.R1707 · Physical Review B

T1

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Abstract

The electronic energy-band structure for RbLaNb2O7, which is closely related to the layered perovskite niobate superconducting KCa2Nb3O10 and metallic KLaNb2O7 with Li intercalation, has been calculated by using the scalar-relativistic full-potential linearized augmented-plane-wave method within the local-density approximation. The result of the calculation shows that this compound is a band insulator with a small gap, and its conduction band is a typical two-dimensional one and the valence band is rather three dimensional. We can conclude that the layered perovskite niobate KCa2Nb3O10 is a band insulator that can be superconducting with electron doping, and have the highly two-dimensional electronic structure.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
KCa2Nb3O10

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5Pressure not reportedunknown

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