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Relaxation effects in the transition temperature of superconducting HgBa2CuO4+δ

S. Sadewasser, J. S. Schilling, J. L. Wagner, O. Chmaissem, J. D. Jorgensen, D. G. Hinks, B. Dabrowski

DOI 10.1103/PhysRevB.60.9827 · Physical Review B

T1

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Abstract

In previous studies on a number of underdoped and overdoped high-temperature superconductors, including YBa2Cu3O7−y and Tl2Ba2CuO6+δ, the transition temperature Tc has been found to change with time in a manner which depends on the sample’s detailed temperature and pressure history. This relaxation behavior in Tc is believed to originate from rearrangements within the oxygen sublattice. In the present high-pressure studies on HgBa2CuO4+δ to 0.8 GPa we find clear evidence for weak relaxation effects in strongly underdoped and overdoped samples (Tc≃40–50K) with an activation energy EA(1bar)≃0.8–0.9eV. For overdoped HgBa2CuO4+δ EA increases under pressure more rapidly than previously observed for YBa2Cu3O6.41, yielding an activation volume of +11±5cm3; the dependence of Tc on pressure is markedly nonlinear, an anomalous result for high-Tc superconductors in the present pressure range, giving evidence for a change in the electronic and/or structural properties near 0.4 GPa.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
HgBa2CuO4+δ

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40Pressure unresolvedonset
HgBa2CuO4+δ

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47.81Pressure unresolvedonset
HgBa2CuO4+δ

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47.55Pressure unresolvedonset
HgBa2CuO4

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98Pressure unresolvedunknown
HgBa2Ca2Cu3O8

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134Pressure unresolvedunknown
HgBa2Ca2Cu3O8

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16430 GPaunknown

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