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Microscopic changes in HoNi2B2C due to thermal treatment and its effect on superconductivity

A. Dertinger, R. E. Dinnebier, A. Kreyssig, P. W. Stephens, S. Pagola, M. Loewenhaupt, S. van Smaalen, H. F. Braun

DOI 10.1103/PhysRevB.63.184518 · Physical Review B

T1

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Abstract

The low-temperature properties of HoNi2B2C strongly depend on its thermodynamic state established via thermal treatment. We present high resolution x-ray powder diffraction data taken on a pair of polycrystalline samples with identical chemical composition (HoNi2B2.1C) but annealed at different temperatures, namely, at 800 and at 1100 °C. Their superconducting transition temperatures differ by more than 10%. Rietveld refinement and difference Fourier analysis reveal subtle differences in the atomic parameters and in the electron density on the carbon site. Furthermore, a new atomic site can be identified for both samples, which is partially occupied with the lighter atoms boron or carbon.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
HoNi2B2.1C

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9.21Pressure not reportedonset
HoNi2B2.1C

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

8.3Pressure not reportedonset

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