Magnetic properties of the low-dimensional cuprate Na5RbCu4(AsO4)4Cl2
J. A. Clayhold, M. Ulutagay-Kartin, S.-J. Hwu, H.-J. Koo, M.-H. Whangbo, A. Voigt, K. Eaiprasertsak
DOI 10.1103/PhysRevB.66.052403 · Physical Review B
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Abstract
The magnetic properties of Na5RbCu4(AsO4)4Cl2 are reported. The material has a layered structure comprised of square Cu4O4 tetramers. The Cu ions are divalent and the system behaves as a low-dimensional S=1/2 antiferromagnet. Spin exchange in Na5RbCu4(AsO4)4Cl2 appears to be quasi-two-dimensional and nonfrustrated. Measurements of the bulk magnetic susceptibility and heat capacity are consistent with low-dimensional magnetism. The compound has an interesting, low-entropy, magnetic transition at T=17 K.
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