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Microstructure and the superconductivity in La2−x−ySrxNayCuO4 systems

Changjin Zhang, Liwei Liu, Li Lu, Yuheng Zhang

DOI 10.1103/PhysRevB.68.174505 · Physical Review B

T1

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Abstract

The mechanism of high-temperature superconductivity is still an open question. Although the relationship between microstructure and superconductivity has been noticed in the early days, there is still lack of a definite explanation. In this paper we study the microstructure and the superconductivity of La2−yNayCuO4 samples and La1.85−ySr0.15NayCuO4 samples. It is surprising that the doping of Na+ does not introduce itinerant hole carriers into the CuO2 plane. All La2−yNayCuO4 samples show insulatorlike behavior just like La2CuO4. For La1.85−ySr0.15NayCuO4 samples, they exhibit superconductivity even at Na doping content y=0.30. We suggest that the microstructure directly dominates the carrier concentration in the CuO2 plane, so that it directly determines the occurrence of the superconductivity.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La2-yNayCuO4

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—Pressure unresolvedunknown
La1.85-ySr0.15NayCuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure unresolvedunknown
La2CuO4

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—Pressure not reportedunknown
La2-xSrxCuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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