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Carbon isotope effect in superconducting MgCNi3

T. Klimczuk, R. J. Cava

DOI 10.1103/PhysRevB.70.212514 · Physical Review B

T1

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Abstract

The effect of carbon isotope substitution on TC in the intermetallic perovskite superconductor MgCNi3 is reported. Four independent groups of samples were synthesized and characterized. The average TC for the C12 samples was found to be 7.12±0.02K and the average TC for the C13 samples was found to be 6.82±0.02K. The resulting carbon isotope effect coefficient is αC=0.540±0.03. This indicates that carbon-based phonons play a critical role in the presence of superconductivity in this compound.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
MgCNi3

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7.12Pressure not reportedunknown
MgC12Ni3

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7.12Pressure not reportedunknown
MgC13Ni3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

6.82Pressure not reportedunknown
Rb3C60

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
YNi2B2C

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—Pressure not reportedunknown
MgB2

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—Pressure not reportedunknown

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