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Clean and dirty superconductivity in pure, Al-doped, and neutron irradiated MgB2: A far-infrared study

M. Ortolani, D. Di Castro, P. Postorino, I. Pallecchi, M. Monni, M. Putti, P. Dore

DOI 10.1103/PhysRevB.71.172508 · Physical Review B

T1

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Abstract

The effects of Al substitution and neutron irradiation on the conduction regime (clean or dirty) of the π and σ band of MgB2 have been investigated by means of far-infrared spectroscopy. The intensity reflected by well characterized polycrystalline samples was measured up to 100cm−1 in both normal and superconducting state. The analysis of the superconducting to normal reflectivity ratios shows that only the effect of the opening of the small gap in the dirty π band can be clearly observed in pure MgB2, consistently with previous results. In Al-doped samples the dirty character of the π band is increased, while no definitive conclusion on the conduction regime of the σ band can be drawn. On the contrary, results obtained for the irradiated sample show that the irradiation-induced disorder drives the σ band in the dirty regime, making the large gap in σ band observable in far-infrared measurements.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
MgB2

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38.5Pressure unresolvedunknown
Mg0.85Al0.15B2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

31Pressure unresolvedunknown
Mg0.7Al0.3B2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

21Pressure unresolvedunknown
MgB2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

35.5Pressure unresolvedunknown

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