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Magnetic properties of the overdoped superconductor La2−xSrxCuO4 with and without Zn impurities

S. Wakimoto, R. J. Birgeneau, A. Kagedan, Hyunkyung Kim, I. Swainson, K. Yamada, H. Zhang

DOI 10.1103/PhysRevB.72.064521 · Physical Review B

T1

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Abstract

The magnetic properties of the Zn-substituted overdoped high-Tc superconductor La2−xSrxCu1−yZnyO4 have been studied by magnetization measurements and neutron scattering. Magnetization measurements reveal that for Zn-free samples with x⩾0.22 a Curie term is induced in the temperature dependence of the magnetic susceptibility implying the existence of local paramagnetic moments. The induced Curie constant corresponds to a moment of 0.5μB per additional Sr2+ ion that exceeds x=0.22. Zn substitution in the overdoped La2−xSrxCuO4 also induces a Curie term that corresponds to 1.2μB per Zn2+ ion, simultaneously suppressing Tc. The relationship between Tc and the magnitude of the Curie term for Zn-free La2−xSrxCuO4 with x⩾0.22 and for Zn-substituted La2−xSrxCuO4 with x=0.22 are closely similar. This signifies a general competitive relationship between the superconductivity and the induced paramagnetic moment. Neutron scattering measurements show that Zn substitution in overdoped La2−xSrxCuO4 anomalously enhances the inelastic magnetic scattering spectra around the (π,π) position, peaking at ω∼7meV. These facts are discussed on the basis of a “swiss-cheese” model of Zn-substituted systems as well as a microscopic phase separation scenario in the overdoped region indicated by muon-spin-relaxation measurements.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La2-xSrxCuO4

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—Pressure not reportedunknown
La2-xSrxCu1-yZnyO4

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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