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Nonlinear susceptibility: Evidence for antiferroquadrupolar fluctuations and a nonmagnetic Γ1 ground state in the heavy fermion superconductor PrOs4Sb12

E. D. Bauer, P.-C. Ho, M. B. Maple, T. Schauerte, D. L. Cox, F. B. Anders

DOI 10.1103/PhysRevB.73.094511 · Physical Review B

T1

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Abstract

Nonlinear susceptibility (χ3) measurements were performed on single crystals of the heavy fermion superconductor PrOs4Sb12 in order to probe the nature of the Pr3+ ground state in the crystalline electric field. Calculations of χ3(T) have been carried out (i) within a mean field model of intersite magnetic and quadrupolar interactions for an ionic (zero hybridization) crystal field Γ1 singlet ground state and a first excited state magnetic triplet, and (ii) within a two-channel Anderson impurity model assuming a Γ23 doublet ground state. The experimental χ3 results are in best agreement with the nonmagnetic Γ1 ground state in the tetrahedral crystalline electric field of the Pr3+ ions with antiferroquadrupolar intersite coupling and weak antiferromagnetic intersite coupling.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
PrOs4Sb12

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

1.85Pressure not reportedunknown

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