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Defect structure of ferromagnetic superconducting RuSr2GdCu2O8

O. I. Lebedev, G. Van Tendeloo, J. P. Attfield, A. C. Mclaughlin

DOI 10.1103/PhysRevB.73.224524 · Physical Review B

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Abstract

The structure and defect structure of superconducting ferromagnetic bulk RuSr2GdCu2O8 has been investigated using high-resolution transmission electron microscopy and high-resolution scanning transmission microscopy. Two distinct, but closely related structures, due to ordering of rotated RuO6 octahedra and due to Cu substitution in the Ru−O layer, have been revealed. The structure of Ru1−xSr2GdCu2+xO8−δ can be described as a periodic alteration along the c axis of CuO4 planes and RuO6 octahedra. The unit-cell parameters of this phase are 2ap×2ap×2c. The possible influence of this phase and defect structure on the sensitivity of the superconductivity and magnetic properties is discussed. Local defects such as 90° domain boundaries, (130) antiphase boundaries, and the associated dislocations are analyzed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
RuSr2GdCu2O8

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37Pressure not reportedunknown
YBa2Cu4O8

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

80Pressure not reportedunknown
Y2Ba4Cu7O15+x

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

40Pressure not reportedunknown

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