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Pressure-induced enhancement of the critical current density in superconducting YBa2Cu3Ox bicrystalline rings

T. Tomita, J. S. Schilling, L. Chen, B. W. Veal, H. Claus

DOI 10.1103/PhysRevB.74.064517 · Physical Review B

T1

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Abstract

The dependence of the critical current density Jc(T) on hydrostatic He-gas pressure to 0.6GPa is determined for nearly optimally doped and strongly underdoped melt-textured YBa2Cu3Ox bicrystalline rings containing single [001]-tilt grain boundaries (GBs) with mismatch angles θ from 0° to 31°. For all samples with θ>0°, Jc is found to increase rapidly under pressure, the rate of increase lying predominantly in the range +20to+50%GPa−1. Within a simple tunneling model, this rate of increase is far too large to be accounted for by a decrease in the GB width W alone. Large oxygen relaxation phenomena in the GB are observed for all rings with finite θ, particularly if they are underdoped. A diagnostic method is introduced (pressure-induced Jc relaxation) which reveals a significant concentration of vacant oxygen sites in the GB region. A concerted effort to fill such sites with oxygen anions, as well as to chemically compress the GB itself, should lead to significant enhancements in Jc under ambient conditions.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3Ox

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91.8Pressure not reportedunknown
YBa2Cu3Ox

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91.2Pressure not reportedunknown
YBa2Cu3Ox

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60.8Pressure not reportedunknown
YBa2Cu3Ox

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92.1Pressure not reportedunknown
YBa2Cu3Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

91.6Pressure not reportedunknown
YBa2Cu3Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

91.5Pressure not reportedunknown
YBa2Cu3Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

60.7Pressure not reportedunknown
YBa2Cu3Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

49.8Pressure not reportedunknown
YBa2Cu3Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

51.8Pressure not reportedunknown
YBa2Cu3Ox

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86.3Pressure not reportedunknown
YBa2Cu4O8

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—Pressure not reportedunknown
Tl2CaBa2Cu2O8+δ

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—Pressure not reportedunknown

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