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Pressure-induced superconductivity in Sc to 74GPa

J. J. Hamlin, J. S. Schilling

DOI 10.1103/PhysRevB.76.012505 · Physical Review B

T1

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Abstract

Using a diamond-anvil cell with nearly hydrostatic helium pressure medium, we have significantly extended the superconducting phase diagram Tc(P) of Sc, the lightest of all transition metals. We find that superconductivity is induced in Sc under pressure, Tc increasing monotonically to 8.2K at 74.2GPa. The Tc(P) dependences of the trivalent d-electron metals Sc, Y, La, and Lu are compared and discussed within a simple s→d charge transfer framework.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Sc

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8.274.2 GPaonset
Sc

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0.3521.5 GPaunknown
Lu

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2.522 GPaunknown

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