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Effect of Mn impurities on the superconductivity in NaxCoO2∙yH2O

Y.-J. Chen, C.-J. Liu, J.-S. Wang, J.-Y. Lin, C. P. Sun, S. W. Huang, J. M. Lee, J. M. Chen, J. F. Lee, D. G. Liu, H. D. Yang

DOI 10.1103/PhysRevB.76.092501 · Physical Review B

T1

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Abstract

To shed light on the symmetry of the superconducting order parameter in NaxCoO2∙yH2O, the Mn doping effects are studied. X-ray absorption spectroscopy verifies that the doped Mn impurities occupy the Co sites and are with a valance close to +4. Impurity scattering by Mn is in the unitary limit that, however, does not lead to strong Tc suppression. This absence of the strong impurity effects on Tc is inconsistent with the simple picture of a sign-changing order parameter. Coexistence of the s-wave superconducting order parameter and the nodal one is proposed to reconcile all the existing experiments and has been implied by the specific heat experiments.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
NaxCoO2*yH2O

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4.5Pressure not reportedonset
NaxCoO2*yH2O

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4.5Pressure not reportedonset
NaxCo1-zMnzO2*yH2O

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—Pressure not reportedonset
NaxCo0.995Mn0.005O2*yH2O

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4.5Pressure not reportedonset
YBa2(Cu1-zZnz)3O6.93

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92Pressure not reportedunknown

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