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Origin of superconductivity in boron-doped silicon carbide from first principles

Jesse Noffsinger, Feliciano Giustino, Steven G. Louie, Marvin L. Cohen

DOI 10.1103/PhysRevB.79.104511 · Physical Review B

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Abstract

We investigate the origin of superconductivity in boron-doped silicon carbide using a first-principles approach. The strength of the electron-phonon coupling calculated for cubic SiC at the experimental doping level suggests that the superconductivity observed in this material is phonon mediated. Analysis of the 2H-SiC, 4H-SiC, 6H-SiC, and 3C-SiC polytypes indicates that superconductivity depends on the stacking of the Si and C layers and that the cubic polytype will exhibit the highest transition temperature. In contrast to the cases of silicon and diamond, acoustic phonons are found to play a major role in the superconductivity of silicon carbide.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
SiC

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1.4Pressure not reportedunknown
SiC

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1.1Pressure not reportedunknown
SiC

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6.3Pressure not reportedunknown
Si

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0.3Pressure not reportedunknown

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