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Superconductivity at 2.3 K in the misfit compound (PbSe)1.16(TiSe2)2

N. Giang, Q. Xu, Y. S. Hor, A. J. Williams, S. E. Dutton, H. W. Zandbergen, R. J. Cava

DOI 10.1103/PhysRevB.82.024503 · Physical Review B

T1

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Abstract

The structural misfit compound (PbSe)1.16(TiSe2)2 is reported. It is a superconductor with a Tc of 2.3 K. (PbSe)1.16(TiSe2)2 derives from a parent compound, TiSe2, which shows a charge-density wave transition and no superconductivity. The crystal structure, characterized by high-resolution electron microscopy and powder x-ray diffraction, consists of two layers of 1T-TiSe2 alternating with a double layer of (100) PbSe. Transport measurements suggest that the superconductivity is induced by charge transfer from the PbSe layers to the TiSe2 layers.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
(PbSe)1.16(TiSe2)2

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2.3Pressure not reportedzero_resistance
(PbSe)1.16(TiSe2)2

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2.3Pressure not reportedonset
TaSe2

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0.15Pressure not reportedunknown
NbSe2

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7.2Pressure not reportedunknown
CuxTiSe2

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4Pressure not reportedunknown

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