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Nanoscale surface element identification and dopant homogeneity in the high-Tc superconductor PrxCa1−xFe2As2

Ilija Zeljkovic, Dennis Huang, Can-Li Song, Bing Lv, Ching-Wu Chu, Jennifer E. Hoffman

DOI 10.1103/PhysRevB.87.201108 · Physical Review B

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Abstract

We use scanning tunneling microscopy to determine the surface structure and dopant distribution in PrxCa1−xFe2As2, the highest-Tc member of the 122 family of iron-based superconductors. We identify the cleaved surface termination by mapping the local tunneling barrier height, related to the work function. We image the individual Pr dopants responsible for superconductivity, and show that they do not cluster, but in fact repel each other at short length scales. We therefore suggest that the low volume fraction high-Tc superconducting phase is unlikely to originate from Pr inhomogeneity.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
PrxCa1-xFe2As2

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43.2Pressure not reportedunknown
KxBa1-xFe2As2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

38Pressure not reportedunknown
Ba(Fe1-xCox)2As2

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25Pressure not reportedunknown
Sm1-xLaxO1-yFyFeAs

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57Pressure not reportedunknown

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