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Superconductivity in Fe1.05Te:Ox single crystals

Z. T. Zhang, Z. R. Yang, W. J. Lu, X. L. Chen, L. Li, Y. P. Sun, C. Y. Xi, L. S. Ling, C. J. Zhang, L. Pi, M. L. Tian, Y. H. Zhang

DOI 10.1103/PhysRevB.88.214511 · Physical Review B

T1

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Abstract

We report the discovery of superconductivity at ∼9 K in Fe1.05Te single crystals that have been exposed to air for more than six months. The superconductivity is induced due to the oxygen incorporation and only exists in the surface layer of the samples. Our high-resolution transmission electron microscopy experiments and density functional theory calculations show the oxygen prefers to locate at the interstitial site in the Fe-Te layer. X-ray photoelectron spectra characterize an enhancement of the itinerant character of Fe 3d electrons, which may reduce the local moment and hence suppress the long-range antiferromagnetism associated with superexchange interactions. This work suggests the bicollinear antiferromagnetism in Fe1+yTe can be suppressed by oxygen incorporation to induce superconductivity and thus could be considered as the parent phase of the superconductivity.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Fe1.05Te:Ox

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9Pressure not reportedonset
Fe1.05Te:Ox

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

8Pressure not reportedonset
Fe1.08Te:Ox

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—Pressure not reportedunknown
Fe1.08Te

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—Pressure not reportedunknown

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