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Strong suppression of coherence effect and appearance of pseudogap in the layered nitride superconductor LixZrNCl: Zr91- and N15-NMR studies

Hisashi Kotegawa, Satoru Oshiro, Yuki Shimizu, Hideki Tou, Yuichi Kasahara, Tsukasa Kishiume, Yasujiro Taguchi, Yoshihiro Iwasa

DOI 10.1103/PhysRevB.90.020503 · Physical Review B

T1

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Abstract

We present NMR measurements of the layered nitride superconductor LixZrNCl. The nuclear spin-lattice relaxation rate 1/T1 shows that the coherence peak is strongly suppressed in LixZrNCl in contrast to conventional BCS superconductors. In the lightly doped region close to the insulating state, the system shows a gaplike behavior, i.e., pseudogap, that is characterized by a reduction in the magnitude of the Knight shift and 1/T1T. A higher superconducting (SC) transition temperature Tc is achieved by coexisting with the pseudogap state. These unusual behaviors, which deviate from the ordinary BCS framework, are the key ingredients to understanding the SC mechanism of LixZrNCl.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
LixZrNCl

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11Pressure not reportedonset
Li0.08ZrNCl

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11Pressure not reportedonset
MgB2

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39Pressure not reportedunknown

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