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Superconducting properties of Rh9In4S4 single crystals

Udhara S. Kaluarachchi, Qisheng Lin, Weiwei Xie, Valentin Taufour, Sergey L. Bud'ko, Gordon J. Miller, Paul C. Canfield

DOI 10.1103/PhysRevB.93.094524 · Physical Review B

T1

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Abstract

The synthesis and crystallographic, thermodynamic, and transport properties of single crystalline Rh9In4S4 were studied. The resistivity, magnetization, and specific heat measurements all clearly indicate bulk superconductivity with a critical temperature, Tc∼2.25 K. The Sommerfeld coefficient γ and the Debye temperature (ΘD) were found to be 34 mJ mol−1 K−2 and 217 K, respectively. The observed specific heat jump, ΔC/γTc=1.66, is larger than the expected BCS weak coupling value of 1.43. Ginzburg-Landau (GL) ratio of the low-temperature GL-penetration depth, λGL≈5750 Å, to the GL-coherence length, ξGL≈94 Å, is large: κ ∼60. Furthermore, we observed a peak effect in the resistivity measurement as a function of both temperature and magnetic field.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Rh9In4S4

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2.25Pressure not reportedzero_resistance
Rh9In4S4

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2.24Pressure not reportedonset
Rh9In4S4

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2.22Pressure not reportedmidpoint
Bi2Rh3.5S2

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1.7Pressure not reportedunknown

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