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Tuning of superconductivity by Ni substitution into noncentrosymmetric ThCo1−xNixC2

T. W. Grant, O. V. Cigarroa, P. F. S. Rosa, A. J. S. Machado, Z. Fisk

DOI 10.1103/PhysRevB.96.014507 · Physical Review B

T1

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Abstract

The recently discovered noncentrosymmetric superconductor ThCoC2 was observed to show unusual superconducting behavior with a critical temperature of Tc=2.65K. Here we investigate the effect of nickel substitution on the superconducting state in ThCo1−xNixC2. Magnetization, resistivity, and heat capacity measurements demonstrate Ni substitution has a dramatic effect with critical temperature increased up to Tc=12.1 K for x=0.4 Ni concentration, which is a rather high transition temperature for a noncentrosymmetric superconductor. In addition, the unusual superconducting characteristics observed in pure ThCoC2 appear to be suppressed or tuned with Ni substitution towards a more conventional fully gapped superconductor.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
ThCoC2

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2.65Pressure not reportedunknown
ThCo1-xNixC2

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12.1Pressure not reportedonset
ThCo1-xNixC2

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12.1Pressure not reportedmidpoint
ThCo1-xNixC2

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11.9Pressure not reportedunknown
LaNiC2

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2.7Pressure not reportedunknown
LaNi1-xCuxC2

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3.4Pressure not reportedunknown
La1-xThxNiC2

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7.9Pressure not reportedunknown

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