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Electronically driven instabilities and superconductivity in the layered La2−xBaxCuO4 perovskites

Jaejun Yu, A. J. Freeman, J. -H. Xu

DOI 10.1103/PhysRevLett.58.1035 · Physical Review Letters

T1

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Abstract

Body-centered tetragonal La2CuO4 is shown to have its electronic structure and properties dominated by the layered in-plane Cu-3d–O-2p interactions. A strong Fermi surface instability along [110] with ‖q‖=2kF leads, via a soft-phonon mode, to the observed orthorhombic phase and accounts for its semiconducting properties. The addition of divalent metals, i.e., Ba, Sr, suppresses the instability and stabilizes the tetragonal phase where the same soft-phonon branch apparently contributes to a large electron-phonon interaction and a high Tc.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La1.85Ba0.15CuO4

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—Pressure not reportedunknown

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