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Superconductivity at 155 K

S. R. Ovshinsky, R. T. Young, D. D. Allred, G. DeMaggio, G. A. Van der Leeden

DOI 10.1103/PhysRevLett.58.2579 · Physical Review Letters

T1

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Abstract

Transition to a superconducting zero-resistance state at 155 K is observed for the first time in bulk material. A new five-element compound has been synthesized with nominal composition Y1Ba2Cu3F2Oy@B. Fluorine plays a critical role in achieving this effect. X-ray diffraction and electron microprobe analysis indicate that the samples are multiphasic. Evidence is presented that the samples contain superconducting phases with onset temperatures considerably above 155 K. Magnetic measurements suggest a flux-trapping effect below 260 K, and diamagnetic deviations from Curie-Weiss behavior in the range 250 K≤T≤100 K indicate a Meissner effect in a small superconducting volume fraction.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3F2Oy

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155Pressure not reportedzero_resistance
YBa2Cu3F2Oy

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168Pressure not reportedzero_resistance
YBa2Cu3F2Oy

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148Pressure not reportedzero_resistance
YBa2Cu3F2Oy

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91Pressure not reportedzero_resistance
YBa2Cu3O7-δ

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95Pressure not reportedonset
YBa2Cu3O7-δ

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90Pressure not reportedzero_resistance
Nb3Ge

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23.2Pressure not reportedunknown

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