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Giant defect-enhanced electron-phonon interactions in ternary copper oxide superconductors

J. C. Phillips

DOI 10.1103/PhysRevLett.59.1856 · Physical Review Letters

T1

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Abstract

A microscopic but schematic model is discussed for defects (such as oxygen vacancies O□) in compounds such as YBa2Cu3O7+δO2−δ□ and La3−xBa3+xCu6O14−δO4−δ□ in relation to the superconductive properties of these materials. The discussion shows in detail how Tc can reach its maximum value at or near the metal-semiconductor transition Tms. It introduces a new mechanism for enhancing of electron-phonon interactions that is separate from, and empirically superior to, Fermi-surface nesting.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La3-xBa3+xCu6O14+δO4-δ

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85Pressure not reportedonset
YBa2Cu3O7-δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
La1.85Sr0.15CuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

35Pressure not reportedunknown
La2.25Ba3.75Cu6O16O2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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