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Symmetry of Hole States in Superconducting Oxides: Correlation with Tc

C. Di Castro, L. F. Feiner, M. Grilli

DOI 10.1103/PhysRevLett.66.3209 · Physical Review Letters

T1

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Abstract

Despite their small occupancy, the apical oxygen pz states have the indirect effect of modifying the relative occupancy of holes in states with different local symmetries in the CuO2 planes. A well-defined correlation is found between the maximum critical temperature Tcmax of various cuprates and the excess of holes in states with local a1 symmetry with respect to the doping δmax at which Tcmax is obtained for each compound. Implications for superconductivity models are discussed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Pb0.5Tl0.5Sr2CaCu2O7

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110Pressure not reportedunknown
La2-xSrxCuO4

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38Pressure not reportedunknown
La2SrCu2O6

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0Pressure not reportedunknown
La1.85Sr0.15CuO4

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38Pressure not reportedunknown
La1.85Ba0.15CuO4

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30Pressure not reportedunknown
(Ba0.67Eu0.33)2(Eu0.67Ce0.33)2Cu3O8.78

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48Pressure not reportedunknown
Y0.8Ca0.2Ba2Cu3O6.11

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50Pressure not reportedunknown
YBa2Cu3O6.5

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

60Pressure not reportedunknown
YBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

93Pressure not reportedunknown
TlBa2CaCu2O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

100Pressure not reportedunknown
Bi2Sr2Ca0.9Y0.1Cu2O8.24

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

93Pressure not reportedunknown

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