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Isotope effect in superconducting Rb3C60

A. P. Ramirez, A. R. Kortan, M. J. Rosseinsky, S. J. Duclos, A. M. Mujsce, R. C. Haddon, D. W. Murphy, A. V. Makhija, S. M. Zahurak, K. B. Lyons

DOI 10.1103/PhysRevLett.68.1058 · Physical Review Letters

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Abstract

Measurements of the superconducting Tc and Raman spectra in isotopically modified Rb3C60 are reported. A decrease in Tc of 0.65±0.10 K in samples with (75±5)% substitution of C13 for C12 yields an exponent of α=0.37±0.05. This interpreted as evidence for phonon-mediated pairing.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Rb3C60

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29.4Pressure not reportedonset

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