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Lorenz Number in High Tc Superconductors: Evidence for Bipolarons

K. K. Lee, A. S. Alexandrov, W. Y. Liang

DOI 10.1103/PhysRevLett.90.217001 · Physical Review Letters

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Abstract

The strong electron-phonon interaction in cuprates has gathered support over the last decade in a number of experiments. While phonons remain almost unrenormalized, electrons are transformed into itinerant bipolarons and thermally excited polarons when the electron-phonon interaction is strong. We calculate the Lorenz number of the system to show that the Wiedemann-Franz law breaks down because of the interference of polaron and bipolaron contributions in the heat flow. The model fits numerically the experimental Hall Lorenz number, which provides direct evidence for bipolarons in the cuprates.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O6+x

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—Pressure not reportedunknown
YBa2Cu3O6.95

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
Tl2Ba2CuO6+δ

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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