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Anomalous Pressure Dependence of the Superconducting Transition Temperature of β-Pyrochlore AOs2O6 Oxides

T. Muramatsu, N. Takeshita, C. Terakura, H. Takagi, Y. Tokura, S. Yonezawa, Y. Muraoka, Z. Hiroi

DOI 10.1103/PhysRevLett.95.167004 · Physical Review Letters

T1

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Abstract

High-pressure effects on the superconducting transitions of β-pyrochlore oxide superconductors AOs2O6 (A=Cs,Rb,K) are studied by measuring resistivity under high pressures up to 10 GPa. The superconducting transition temperature Tc first increases with increasing pressure in every compound and then exhibits a broad maximum at 7.6 K (6 GPa), 8.2 K (2 GPa), and 10 K (0.6 GPa) for A=Cs, Rb, and K, respectively. Finally, the superconductivity is suppressed completely at a critical pressure near 7 GPa and 6 GPa for A=Rb and K and probably above 10 GPa for A=Cs. Characteristic changes in the coefficient A of the T2 term in resistivity and residual resistivity are observed, both of which are synchronized with the corresponding change in Tc.

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FormulaReported Tc (K)Pressure (GPa)Type
CsOs2O6

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3.3Pressure unresolvedunknown
RbOs2O6

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6.3Pressure unresolvedunknown
KOs2O6

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9.6Pressure unresolvedunknown
CsOs2O6

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7.66 GPamidpoint
RbOs2O6

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8.22 GPamidpoint
KOs2O6

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100.6 GPamidpoint

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