Topotactically induced oxygen vacancy order in nickelate single crystals

Yu-Mi Wu; Pascal Puphal; Hangoo Lee; Jürgen Nuss; Masahiko Isobe; Bernhard Keimer; Matthias Hepting; Y. Eren Suyolcu; Peter A. van Aken

doi:10.1103/PhysRevMaterials.7.053609

Topotactically induced oxygen vacancy order in nickelate single crystals

Yu-Mi Wu, Pascal Puphal, Hangoo Lee, Jürgen Nuss, Masahiko Isobe, Bernhard Keimer, Matthias Hepting, Y. Eren Suyolcu, Peter A. van Aken

DOI 10.1103/PhysRevMaterials.7.053609 · Physical Review Materials

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Abstract

The strong structure-property coupling in rare-earth nickelates has spurred the realization of new quantum phases in rapid succession. Recently, topotactic transformations have provided a new platform for the controlled creation of oxygen vacancies and, therewith, for the exploitation of such coupling in nickelates. Here, we report the emergence of oxygen vacancy ordering in Pr0.92Ca0.08NiO2.75 single crystals obtained via a topotactic reduction of the perovskite phase Pr0.92Ca0.08NiO3, using CaH2 as the reducing agent. We unveil a brownmillerite-like ordering pattern of the vacancies by high-resolution scanning transmission electron microscopy, with Ni ions in alternating square-pyramidal and octahedral coordination along the pseudocubic [100] direction. Furthermore, we find that the crystal structure acquires a high level of internal strain, where wavelike modulations of polyhedral tilts and rotations accommodate the large distortions around the vacancy sites. Our results suggest that atomic-resolution electron microscopy is a powerful method to locally resolve unconventional crystal structures that result from the topotactic transformation of complex oxide materials.